High oxidation state alkali-metal late-transition-metal oxides

D.B. Currie; A.L. Hector; E.A. Raekelboom; J.R. Owen; M.T. Weller

High oxidation state alkali-metal late-transition-metal oxides

D.B. Currie
, A.L. Hector
, E.A. Raekelboom
, J.R. Owen
, M.T. Weller

Department of Chemistry

University of Southampton

Research output: Contribution to journal › Article › peer-review

Abstract

Li2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.

Original language	English
Journal	Materials Research Society Symposium Proceedings
Volume	658
Publication status	Published - 2001

Cite this

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title = "High oxidation state alkali-metal late-transition-metal oxides",

abstract = "Li2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.",

author = "D.B. Currie and A.L. Hector and E.A. Raekelboom and J.R. Owen and M.T. Weller",

year = "2001",

language = "English",

volume = "658",

journal = "Materials Research Society Symposium Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

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TY - JOUR

T1 - High oxidation state alkali-metal late-transition-metal oxides

AU - Currie, D.B.

AU - Hector, A.L.

AU - Raekelboom, E.A.

AU - Owen, J.R.

AU - Weller, M.T.

PY - 2001

Y1 - 2001

N2 - Li2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.

AB - Li2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.

UR - https://www.scopus.com/pages/publications/0035560292

M3 - Article

AN - SCOPUS:0035560292

SN - 0272-9172

VL - 658

JO - Materials Research Society Symposium Proceedings

JF - Materials Research Society Symposium Proceedings

ER -

High oxidation state alkali-metal late-transition-metal oxides

Abstract

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