Heterometallic cobalt(ii)-titanium(iv) oxo cages; Key building blocks for hybrid materials

S Eslava; F. Hengesbach; M. McPartlin; D.S. Wright

doi:10.1039/c0cc00016g

Heterometallic cobalt(ii)-titanium(iv) oxo cages; Key building blocks for hybrid materials

S Eslava, F. Hengesbach, M. McPartlin, D.S. Wright

Department of Chemical Engineering

University of Cambridge

Research output: Contribution to journal › Article › peer-review

43 Citations (SciVal)

Abstract

The two new heterometallic cobalt(ii)/titanium oxo cages octanuclear [TiO(OEt)(CoCl)] (1) and pentanuclear [TiO(OEt)(CoCl)] (2) have been obtained via condensation reactions of Ti(OEt) in the presence of CoCl . This simple methodology gives access to key well-defined molecular building blocks for Co-doped hybrid materials.

Original language	English
Pages (from-to)	4701-4703
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	26
DOIs	https://doi.org/10.1039/c0cc00016g
Publication status	Published - 14 Jul 2010

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abstract = "The two new heterometallic cobalt(ii)/titanium oxo cages octanuclear [TiO(OEt)(CoCl)] (1) and pentanuclear [TiO(OEt)(CoCl)] (2) have been obtained via condensation reactions of Ti(OEt) in the presence of CoCl . This simple methodology gives access to key well-defined molecular building blocks for Co-doped hybrid materials.",

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AU - McPartlin, M.

AU - Wright, D.S.

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AB - The two new heterometallic cobalt(ii)/titanium oxo cages octanuclear [TiO(OEt)(CoCl)] (1) and pentanuclear [TiO(OEt)(CoCl)] (2) have been obtained via condensation reactions of Ti(OEt) in the presence of CoCl . This simple methodology gives access to key well-defined molecular building blocks for Co-doped hybrid materials.

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Heterometallic cobalt(ii)-titanium(iv) oxo cages; Key building blocks for hybrid materials

Abstract

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