Despite the routine employment of Grignard reagents and Hauser bases as stoichiometric carbanion reagents in organic and inorganic synthesis, a defined reaction chemistry encompassing the heavier elements of Group II (M=Ca, Sr and Ba) has, until recently, remained unreported. This article provides details of the recent progress in heavier Group II catalysed small molecule transformations mediated by well-defined heteroleptic and homoleptic complexes of the form LMX or MX2; where L is a mono-anionic ligand and X is a reactive s-bonded substituent. The intra-and intermolecular heterofunctionalization (hydroamination, hydrophosphination, hydrosilylation and hydrogenation) of alkenes, alkynes, dienes, carbodiimides, isocyanates and ketones is discussed.
|Number of pages||37|
|Journal||Proceedings of the Royal Society of London Series A - Mathematical Physical and Engineering Sciences|
|Publication status||Published - 8 Apr 2010|
- synthesis (chemical)
- barium compounds
- calcium alloys
Barrett, A. G. M., Crimmin, M. R., Hill, M. S., & Procopiou, P. A. (2010). Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium. Proceedings of the Royal Society of London Series A - Mathematical Physical and Engineering Sciences, 466(2116), 927-963. https://doi.org/10.1098/rspa.2009.0558