Heterobimetallic s-block hydrides by σ-bond metathesis

D.J. Liptrot; M.S. Hill; M.F. Mahon

doi:10.1002/chem.201403215

Heterobimetallic s-block hydrides by σ-bond metathesis

D.J. Liptrot, M.S. Hill, M.F. Mahon

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37 Citations (SciVal)

Abstract

Reactions between PhSiH₃ and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe₃)₂}₂MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe₃)₂}₂MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.

Original language	English
Pages (from-to)	9871-9874
Journal	Chemistry - A European Journal
Volume	20
Issue number	32
Early online date	7 Jul 2014
DOIs	https://doi.org/10.1002/chem.201403215
Publication status	Published - 4 Aug 2014

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10.1002/chem.201403215

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title = "Heterobimetallic s-block hydrides by σ-bond metathesis",

abstract = "Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.",

author = "D.J. Liptrot and M.S. Hill and M.F. Mahon",

year = "2014",

month = aug,

day = "4",

doi = "10.1002/chem.201403215",

language = "English",

volume = "20",

pages = "9871--9874",

journal = "Chemistry - A European Journal",

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T1 - Heterobimetallic s-block hydrides by σ-bond metathesis

AU - Liptrot, D.J.

AU - Hill, M.S.

AU - Mahon, M.F.

PY - 2014/8/4

Y1 - 2014/8/4

N2 - Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.

AB - Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.

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UR - http://dx.doi.org/10.1002/chem.201403215

U2 - 10.1002/chem.201403215

DO - 10.1002/chem.201403215

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SN - 0947-6539

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SP - 9871

EP - 9874

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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ER -

Heterobimetallic s-block hydrides by σ-bond metathesis

Abstract

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Heterobimetallic s-block hydrides by σ-bond metathesis

Abstract

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Group 2: Elements of 21st Century Catalysis

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MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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