Heterobimetallic s-block hydrides by σ-bond metathesis

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.

Original languageEnglish
Pages (from-to)9871-9874
JournalChemistry - A European Journal
Volume20
Issue number32
Early online date7 Jul 2014
DOIs
Publication statusPublished - 4 Aug 2014

Fingerprint

Alkali Metals
Hydrides
Metals

Cite this

Heterobimetallic s-block hydrides by σ-bond metathesis. / Liptrot, D.J.; Hill, M.S.; Mahon, M.F.

In: Chemistry - A European Journal, Vol. 20, No. 32, 04.08.2014, p. 9871-9874.

Research output: Contribution to journalArticle

@article{bf71d004b41341ee977b9845198c9302,
title = "Heterobimetallic s-block hydrides by σ-bond metathesis",
abstract = "Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.",
author = "D.J. Liptrot and M.S. Hill and M.F. Mahon",
year = "2014",
month = "8",
day = "4",
doi = "10.1002/chem.201403215",
language = "English",
volume = "20",
pages = "9871--9874",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "32",

}

TY - JOUR

T1 - Heterobimetallic s-block hydrides by σ-bond metathesis

AU - Liptrot, D.J.

AU - Hill, M.S.

AU - Mahon, M.F.

PY - 2014/8/4

Y1 - 2014/8/4

N2 - Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.

AB - Reactions between PhSiH3 and alkali-metal diamidoalkylmagnesiates ([M{N(SiMe3)2}2MgBu], M=Li, Na, K) provide either selective alkyl metathesis or the formation of polyhydride aggregates contingent upon the identity of the Group1 metal. In the case of [M{N(SiMe3)2}2MgBu], this reactivity results in a structurally unprecedented dodecametallic decahydride cluster species.

UR - http://www.scopus.com/inward/record.url?scp=84903682405&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1002/chem.201403215

U2 - 10.1002/chem.201403215

DO - 10.1002/chem.201403215

M3 - Article

VL - 20

SP - 9871

EP - 9874

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 32

ER -