Hetero-epitaxial approach by using labile coordination sites to prepare catenated metal-organic frameworks with high surface areas

Nianyong Zhu; Matthew Lennox; Gerard Tobin; Lisa Goodman; Tina Düren; Wolfgang Schmitt

doi:10.1002/chem.201304856

Hetero-epitaxial approach by using labile coordination sites to prepare catenated metal-organic frameworks with high surface areas

Nianyong Zhu, Matthew Lennox, Gerard Tobin, Lisa Goodman, Tina Düren, Wolfgang Schmitt

Research output: Contribution to journal › Article › peer-review

16 Citations (SciVal)

Abstract

A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a "topological blueprint". The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented Cu^II acetate-based MOFs.

Original language	English
Pages (from-to)	3595-3599
Number of pages	5
Journal	Chemistry - A European Journal
Volume	20
Issue number	13
DOIs	https://doi.org/10.1002/chem.201304856
Publication status	Published - 24 Mar 2014

Keywords

coordination chemistry
copper
epitaxy
metal-organic frameworks
supramolecular chemistry

ASJC Scopus subject areas

General Chemistry

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10.1002/chem.201304856

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abstract = "A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a {"}topological blueprint{"}. The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented CuII acetate-based MOFs.",

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AU - Zhu, Nianyong

AU - Lennox, Matthew

AU - Tobin, Gerard

AU - Goodman, Lisa

AU - Düren, Tina

AU - Schmitt, Wolfgang

PY - 2014/3/24

Y1 - 2014/3/24

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AB - A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a "topological blueprint". The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented CuII acetate-based MOFs.

KW - coordination chemistry

KW - copper

KW - epitaxy

KW - metal-organic frameworks

KW - supramolecular chemistry

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ER -

Hetero-epitaxial approach by using labile coordination sites to prepare catenated metal-organic frameworks with high surface areas

Abstract

Keywords

ASJC Scopus subject areas

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