Heavier group 2 element-catalysed hydroamination of isocyanates

Anthony G.M. Barrett; Tanya C. Boorman; Mark R. Crimmin; Michael S. Hill; Gabriele Kociok-Köhn; Panayiotis A. Procopiou

doi:10.1039/b809649j

Heavier group 2 element-catalysed hydroamination of isocyanates

Anthony G.M. Barrett, Tanya C. Boorman, Mark R. Crimmin, Michael S. Hill, Gabriele Kociok-Köhn, Panayiotis A. Procopiou

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR ₂)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe₃, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe₃) ₂}₂] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

Original language	English
Pages (from-to)	5206-5208
Number of pages	3
Journal	Chemical Communications
Issue number	41
DOIs	https://doi.org/10.1039/b809649j
Publication status	Published - 2008

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b809649j

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title = "Heavier group 2 element-catalysed hydroamination of isocyanates",

abstract = "The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR 2)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe3, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe3) 2}2] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.",

author = "Barrett, {Anthony G.M.} and Boorman, {Tanya C.} and Crimmin, {Mark R.} and Hill, {Michael S.} and Gabriele Kociok-K{\"o}hn and Procopiou, {Panayiotis A.}",

year = "2008",

doi = "10.1039/b809649j",

language = "English",

pages = "5206--5208",

journal = "Chemical communications (Cambridge, England)",

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publisher = "Royal Society of Chemistry",

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T1 - Heavier group 2 element-catalysed hydroamination of isocyanates

AU - Barrett, Anthony G.M.

AU - Boorman, Tanya C.

AU - Crimmin, Mark R.

AU - Hill, Michael S.

AU - Kociok-Köhn, Gabriele

AU - Procopiou, Panayiotis A.

PY - 2008

Y1 - 2008

N2 - The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR 2)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe3, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe3) 2}2] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

AB - The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR 2)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe3, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe3) 2}2] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

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U2 - 10.1039/b809649j

DO - 10.1039/b809649j

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