Heavier group 2 element-catalysed hydroamination of isocyanates

Anthony G.M. Barrett, Tanya C. Boorman, Mark R. Crimmin, Michael S. Hill, Gabriele Kociok-Köhn, Panayiotis A. Procopiou

Research output: Contribution to journalArticlepeer-review

45 Citations (Scopus)

Abstract

The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR 2)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe3, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe3) 2}2] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

Original languageEnglish
Pages (from-to)5206-5208
Number of pages3
JournalChemical Communications
Issue number41
DOIs
Publication statusPublished - 2008

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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