Heavier alkaline earth amides as catalysts for the Tischenko reaction

Mark R. Crimmin; Anthony G.M. Barrett; Michael S. Hill; Panayiotis A. Procopiou

doi:10.1021/ol0627247

Heavier alkaline earth amides as catalysts for the Tischenko reaction

Mark R. Crimmin, Anthony G.M. Barrett, Michael S. Hill, Panayiotis A. Procopiou

Research output: Contribution to journal › Article › peer-review

97 Citations (SciVal)

Abstract

(Chemical Equation Presented) Homoleptic heavier alkaline earth amides, M{N(SiMe₃)₂}₂(THF)₂ (M = Ca, Sr, and Ba) are reported as precatalysts for the dimerization of aldehydes to the analogous carboxylic esters (Tischenko reaction).

Original language	English
Pages (from-to)	331-333
Number of pages	3
Journal	Organic Letters
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/ol0627247
Publication status	Published - 18 Jan 2007

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0627247

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title = "Heavier alkaline earth amides as catalysts for the Tischenko reaction",

abstract = "(Chemical Equation Presented) Homoleptic heavier alkaline earth amides, M\{N(SiMe3)2\}2(THF)2 (M = Ca, Sr, and Ba) are reported as precatalysts for the dimerization of aldehydes to the analogous carboxylic esters (Tischenko reaction).",

author = "Crimmin, \{Mark R.\} and Barrett, \{Anthony G.M.\} and Hill, \{Michael S.\} and Procopiou, \{Panayiotis A.\}",

year = "2007",

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doi = "10.1021/ol0627247",

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journal = "Organic Letters",

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AU - Crimmin, Mark R.

AU - Barrett, Anthony G.M.

AU - Hill, Michael S.

AU - Procopiou, Panayiotis A.

PY - 2007/1/18

Y1 - 2007/1/18

N2 - (Chemical Equation Presented) Homoleptic heavier alkaline earth amides, M{N(SiMe3)2}2(THF)2 (M = Ca, Sr, and Ba) are reported as precatalysts for the dimerization of aldehydes to the analogous carboxylic esters (Tischenko reaction).

AB - (Chemical Equation Presented) Homoleptic heavier alkaline earth amides, M{N(SiMe3)2}2(THF)2 (M = Ca, Sr, and Ba) are reported as precatalysts for the dimerization of aldehydes to the analogous carboxylic esters (Tischenko reaction).

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U2 - 10.1021/ol0627247

DO - 10.1021/ol0627247

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AN - SCOPUS:33846617307

SN - 1523-7060

VL - 9

SP - 331

EP - 333

JO - Organic Letters

JF - Organic Letters

IS - 2

ER -

Heavier alkaline earth amides as catalysts for the Tischenko reaction

Abstract

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