Halide abstraction from [(η5-C5H 5)NbCl4] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η5-C5H5)NbCl(MeCN)4] 3+[(η5-C5H5)Nb(MeCN) 6]4+...

Gerald R. Willey; Mark L. Butcher; Timothy J. Woodman; Michael G.B. Drew

doi:10.1039/C39940002721

Halide abstraction from [(η⁵-C₅H ₅)NbCl₄] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η⁵-C₅H₅)NbCl(MeCN)₄] ³⁺[(η⁵-C₅H₅)Nb(MeCN) ₆]⁴⁺...

Gerald R. Willey
, Mark L. Butcher
, Timothy J. Woodman
, Michael G.B. Drew

University of Warwick
University of Reading

Research output: Contribution to journal › Article › peer-review

Abstract

Title full: Halide abstraction from [(η⁵-C₅H ₅)NbCl₄] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η⁵-C₅H₅)NbCl(MeCN)₄] ³⁺[(η⁵-C₅H₅)Nb(MeCN) ₆]⁴⁺[SbCl₆]₇·7MeCN. Sequential removal of chloride ions from [(η⁵-C ₅H₅)NbCl₄] can be realised using antimony(V) chloride in acetonitrile under controlled stoichiometry; the formation and structural characterisation of the novel Nb(V) cations [(η⁵- C₅H₅)NbCl(MeCN)₄]³⁺ and ([η⁵-C₅H₅)Nb(MeCN)₆] ⁴⁺ are described.

Original language	English
Pages (from-to)	2721-2722
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39940002721
Publication status	Published - 31 Dec 1994

ASJC Scopus subject areas

Molecular Medicine

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Willey, G. R., Butcher, M. L., Woodman, T. J., & Drew, M. G. B. (1994). Halide abstraction from [(η⁵-C₅H ₅)NbCl₄] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η⁵-C₅H₅)NbCl(MeCN)₄] ³⁺[(η⁵-C₅H₅)Nb(MeCN) ₆]⁴⁺... Journal of the Chemical Society, Chemical Communications, (23), 2721-2722. https://doi.org/10.1039/C39940002721

Halide abstraction from [(η⁵-C₅H ₅)NbCl₄] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η⁵-C₅H₅)NbCl(MeCN)₄] ³⁺[(η⁵-C₅H₅)Nb(MeCN) ₆]⁴⁺... / Willey, Gerald R.; Butcher, Mark L.; Woodman, Timothy J. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 23, 31.12.1994, p. 2721-2722.

Research output: Contribution to journal › Article › peer-review

Willey, GR, Butcher, ML , Woodman, TJ & Drew, MGB 1994, 'Halide abstraction from [(η⁵-C₅H ₅)NbCl₄] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η⁵-C₅H₅)NbCl(MeCN)₄] ³⁺[(η⁵-C₅H₅)Nb(MeCN) ₆]⁴⁺...', Journal of the Chemical Society, Chemical Communications, no. 23, pp. 2721-2722. https://doi.org/10.1039/C39940002721

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title = "Halide abstraction from [(η5-C5H 5)NbCl4] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η5-C5H5)NbCl(MeCN)4] 3+[(η5-C5H5)Nb(MeCN) 6]4+...",

abstract = "Title full: Halide abstraction from [(η5-C5H 5)NbCl4] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η5-C5H5)NbCl(MeCN)4] 3+[(η5-C5H5)Nb(MeCN) 6]4+[SbCl6]7·7MeCN. Sequential removal of chloride ions from [(η5-C 5H5)NbCl4] can be realised using antimony(V) chloride in acetonitrile under controlled stoichiometry; the formation and structural characterisation of the novel Nb(V) cations [(η5- C5H5)NbCl(MeCN)4]3+ and ([η5-C5H5)Nb(MeCN)6] 4+ are described.",

author = "Willey, \{Gerald R.\} and Butcher, \{Mark L.\} and Woodman, \{Timothy J.\} and Drew, \{Michael G.B.\}",

year = "1994",

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AB - Title full: Halide abstraction from [(η5-C5H 5)NbCl4] leading to novel cationic niobium(V) species: Crystal structure of the 'double' hexachloroantimonate(V) salt [(η5-C5H5)NbCl(MeCN)4] 3+[(η5-C5H5)Nb(MeCN) 6]4+[SbCl6]7·7MeCN. Sequential removal of chloride ions from [(η5-C 5H5)NbCl4] can be realised using antimony(V) chloride in acetonitrile under controlled stoichiometry; the formation and structural characterisation of the novel Nb(V) cations [(η5- C5H5)NbCl(MeCN)4]3+ and ([η5-C5H5)Nb(MeCN)6] 4+ are described.

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