Gold-catalyzed rearrangement of O-vinyl oximes for the synthesis of highly substituted pyrroles

Simbarashe Ngwerume; Jason E. Camp

doi:10.1039/C0CC04372A

Gold-catalyzed rearrangement of O-vinyl oximes for the synthesis of highly substituted pyrroles

Simbarashe Ngwerume, Jason E. Camp

Department of Chemistry

University of Nottingham

Research output: Contribution to journal › Article › peer-review

62 Citations (SciVal)

Abstract

O-Vinyl oximes were synthesized from the reaction of oximes with activated alkynes and subsequently rearranged using gold catalysis to afford highly substituted pyrroles in an efficient and regiocontrolled process. Addnl., pyrroles were formed directly from oximes and activated alkynes in a multifaceted catalysis process.

Original language	English
Pages (from-to)	1857-1859
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	6
Early online date	6 Dec 2010
DOIs	https://doi.org/10.1039/C0CC04372A
Publication status	Published - 2011

Bibliographical note

M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved.

CAPLUS AN 2011:121290(Journal)

Keywords

Vinyl oxime prepn rearrangement gold catalyst
acetylenecarboxylate ketoxime addn

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abstract = "O-Vinyl oximes were synthesized from the reaction of oximes with activated alkynes and subsequently rearranged using gold catalysis to afford highly substituted pyrroles in an efficient and regiocontrolled process. Addnl., pyrroles were formed directly from oximes and activated alkynes in a multifaceted catalysis process. ",

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AB - O-Vinyl oximes were synthesized from the reaction of oximes with activated alkynes and subsequently rearranged using gold catalysis to afford highly substituted pyrroles in an efficient and regiocontrolled process. Addnl., pyrroles were formed directly from oximes and activated alkynes in a multifaceted catalysis process.

KW - Vinyl oxime prepn rearrangement gold catalyst

KW - acetylenecarboxylate ketoxime addn

U2 - 10.1039/C0CC04372A

DO - 10.1039/C0CC04372A

M3 - Article

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VL - 47

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EP - 1859

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Gold-catalyzed rearrangement of O-vinyl oximes for the synthesis of highly substituted pyrroles

Abstract

Bibliographical note

Keywords

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