Glycidyl methacrylate and N-vinylpyrrolidinone copolymers: synthesis and nuclear magnetic resonance characterization

T. C. Hunter; G. J. Price

doi:10.1016/0032-3861(94)90919-9

Glycidyl methacrylate and N-vinylpyrrolidinone copolymers: synthesis and nuclear magnetic resonance characterization

T. C. Hunter, G. J. Price

Department of Chemistry

University of Bath

Research output: Contribution to journal › Article › peer-review

Abstract

Poly(glycidyl methacrylate) and water-soluble copolymers of glycidyl methacrylate with N-vinylpyrrolidinone were prepared by free-radical-initiated solution polymerization in chloroform. Polymer microstructure was investigated by high-field ¹H and ¹³C nuclear magnetic resonance (n.m.r.), ¹H decoupled ¹³C n.m.r., ¹H¹³C correlation n.m.r. and 135 DEPT (distortionless enhancement by polarization transfer) n.m.r. The combined use of these techniques allowed unequivocal ¹³C and ¹H n.m.r. assignments of carbons and protons to be established. Copolymer composition was thus determined from ¹H n.m.r.

Original language	English
Pages (from-to)	3530-3534
Number of pages	5
Journal	Polymer
Volume	35
Issue number	16
DOIs	https://doi.org/10.1016/0032-3861(94)90919-9
Publication status	Published - Aug 1994

Keywords

n.m.r. characterization
poly(glycidyl methacrylate)
vinylpyrrolidinone copolymers

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics

Access to Document

10.1016/0032-3861(94)90919-9

Cite this

@article{6000551a746c433db35fde0696b88c49,

title = "Glycidyl methacrylate and N-vinylpyrrolidinone copolymers: synthesis and nuclear magnetic resonance characterization",

abstract = "Poly(glycidyl methacrylate) and water-soluble copolymers of glycidyl methacrylate with N-vinylpyrrolidinone were prepared by free-radical-initiated solution polymerization in chloroform. Polymer microstructure was investigated by high-field 1H and 13C nuclear magnetic resonance (n.m.r.), 1H decoupled 13C n.m.r., 1H13C correlation n.m.r. and 135 DEPT (distortionless enhancement by polarization transfer) n.m.r. The combined use of these techniques allowed unequivocal 13C and 1H n.m.r. assignments of carbons and protons to be established. Copolymer composition was thus determined from 1H n.m.r.",

keywords = "n.m.r. characterization, poly(glycidyl methacrylate), vinylpyrrolidinone copolymers",

author = "Hunter, {T. C.} and Price, {G. J.}",

year = "1994",

month = aug,

doi = "10.1016/0032-3861(94)90919-9",

language = "English",

volume = "35",

pages = "3530--3534",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier",

number = "16",

}

TY - JOUR

T1 - Glycidyl methacrylate and N-vinylpyrrolidinone copolymers

T2 - synthesis and nuclear magnetic resonance characterization

AU - Hunter, T. C.

AU - Price, G. J.

PY - 1994/8

Y1 - 1994/8

N2 - Poly(glycidyl methacrylate) and water-soluble copolymers of glycidyl methacrylate with N-vinylpyrrolidinone were prepared by free-radical-initiated solution polymerization in chloroform. Polymer microstructure was investigated by high-field 1H and 13C nuclear magnetic resonance (n.m.r.), 1H decoupled 13C n.m.r., 1H13C correlation n.m.r. and 135 DEPT (distortionless enhancement by polarization transfer) n.m.r. The combined use of these techniques allowed unequivocal 13C and 1H n.m.r. assignments of carbons and protons to be established. Copolymer composition was thus determined from 1H n.m.r.

AB - Poly(glycidyl methacrylate) and water-soluble copolymers of glycidyl methacrylate with N-vinylpyrrolidinone were prepared by free-radical-initiated solution polymerization in chloroform. Polymer microstructure was investigated by high-field 1H and 13C nuclear magnetic resonance (n.m.r.), 1H decoupled 13C n.m.r., 1H13C correlation n.m.r. and 135 DEPT (distortionless enhancement by polarization transfer) n.m.r. The combined use of these techniques allowed unequivocal 13C and 1H n.m.r. assignments of carbons and protons to be established. Copolymer composition was thus determined from 1H n.m.r.

KW - n.m.r. characterization

KW - poly(glycidyl methacrylate)

KW - vinylpyrrolidinone copolymers

UR - http://www.scopus.com/inward/record.url?scp=43949158024&partnerID=8YFLogxK

U2 - 10.1016/0032-3861(94)90919-9

DO - 10.1016/0032-3861(94)90919-9

M3 - Article

AN - SCOPUS:43949158024

SN - 0032-3861

VL - 35

SP - 3530

EP - 3534

JO - Polymer

JF - Polymer

IS - 16

ER -

Glycidyl methacrylate and N-vinylpyrrolidinone copolymers: synthesis and nuclear magnetic resonance characterization

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this