Glucose-Derived Palladium(0) Nanoparticles as in Situ-Formed Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Isopropanol.

Jason E. Camp; Jay J. Dunsford; Edward P. Cannons; William J. Restorick; Anastasia Gadzhieva; Michael W. Fay; Robert J. Smith

doi:10.1021/sc400410v

Glucose-Derived Palladium(0) Nanoparticles as in Situ-Formed Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Isopropanol.

Jason E. Camp, Jay J. Dunsford, Edward P. Cannons, William J. Restorick, Anastasia Gadzhieva, Michael W. Fay, Robert J. Smith

Department of Chemistry

University of Nottingham

Research output: Contribution to journal › Article › peer-review

44 Citations (SciVal)

Abstract

Effective and convenient protocols using renewable sugar-derived palladium(0) nanoparticles (PdNPs) as in situ-formed catalysts for Suzuki-Miyaura cross-coupling reactions in isopropanol under thermal and microwave heating conditions have been developed. The addn. of a small amt. of glucose (5 mol %) to the reaction mixt. lead to an increase in yield of the cross-coupled products compared to control expts. that omitted glucose. The size and morphol. of the in situ-formed PdNPs were detd. by TEM, and further EF-TEM anal. showed a hydrophilic hydroxylated shell around the individual palladium particles. The polar/hydrophilic nature of the nanoparticles allowed for their facile removal from the cross-coupled product, and a significant decrease in the amt. of palladium incorporated into the final product was obsd., as measured by ICP-MS anal. [on SciFinder(R)]

Original language	English
Pages (from-to)	500-505
Number of pages	6
Journal	ACS Sustainable Chemisty and Engineering
Volume	2
Issue number	3
DOIs	https://doi.org/10.1021/sc400410v
Publication status	Published - 2014

Bibliographical note

M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved.

CAPLUS AN 2013:1789466(Journal; Online Computer File)

Keywords

glucose palladium nanoparticle catalyst Suzuki Miyaura cross coupling

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/sc400410v

Cite this

@article{228a38ede2804f3a9ced99c2576822f4,

title = "Glucose-Derived Palladium(0) Nanoparticles as in Situ-Formed Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Isopropanol.",

abstract = "Effective and convenient protocols using renewable sugar-derived palladium(0) nanoparticles (PdNPs) as in situ-formed catalysts for Suzuki-Miyaura cross-coupling reactions in isopropanol under thermal and microwave heating conditions have been developed. The addn. of a small amt. of glucose (5 mol %) to the reaction mixt. lead to an increase in yield of the cross-coupled products compared to control expts. that omitted glucose. The size and morphol. of the in situ-formed PdNPs were detd. by TEM, and further EF-TEM anal. showed a hydrophilic hydroxylated shell around the individual palladium particles. The polar/hydrophilic nature of the nanoparticles allowed for their facile removal from the cross-coupled product, and a significant decrease in the amt. of palladium incorporated into the final product was obsd., as measured by ICP-MS anal. [on SciFinder(R)]",

keywords = "glucose palladium nanoparticle catalyst Suzuki Miyaura cross coupling",

author = "Camp, {Jason E.} and Dunsford, {Jay J.} and Cannons, {Edward P.} and Restorick, {William J.} and Anastasia Gadzhieva and Fay, {Michael W.} and Smith, {Robert J.}",

year = "2014",

doi = "10.1021/sc400410v",

language = "English",

volume = "2",

pages = "500--505",

journal = "ACS Sustainable Chemisty and Engineering ",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Glucose-Derived Palladium(0) Nanoparticles as in Situ-Formed Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Isopropanol.

AU - Camp, Jason E.

AU - Dunsford, Jay J.

AU - Cannons, Edward P.

AU - Restorick, William J.

AU - Gadzhieva, Anastasia

AU - Fay, Michael W.

AU - Smith, Robert J.

PY - 2014

Y1 - 2014

N2 - Effective and convenient protocols using renewable sugar-derived palladium(0) nanoparticles (PdNPs) as in situ-formed catalysts for Suzuki-Miyaura cross-coupling reactions in isopropanol under thermal and microwave heating conditions have been developed. The addn. of a small amt. of glucose (5 mol %) to the reaction mixt. lead to an increase in yield of the cross-coupled products compared to control expts. that omitted glucose. The size and morphol. of the in situ-formed PdNPs were detd. by TEM, and further EF-TEM anal. showed a hydrophilic hydroxylated shell around the individual palladium particles. The polar/hydrophilic nature of the nanoparticles allowed for their facile removal from the cross-coupled product, and a significant decrease in the amt. of palladium incorporated into the final product was obsd., as measured by ICP-MS anal. [on SciFinder(R)]

AB - Effective and convenient protocols using renewable sugar-derived palladium(0) nanoparticles (PdNPs) as in situ-formed catalysts for Suzuki-Miyaura cross-coupling reactions in isopropanol under thermal and microwave heating conditions have been developed. The addn. of a small amt. of glucose (5 mol %) to the reaction mixt. lead to an increase in yield of the cross-coupled products compared to control expts. that omitted glucose. The size and morphol. of the in situ-formed PdNPs were detd. by TEM, and further EF-TEM anal. showed a hydrophilic hydroxylated shell around the individual palladium particles. The polar/hydrophilic nature of the nanoparticles allowed for their facile removal from the cross-coupled product, and a significant decrease in the amt. of palladium incorporated into the final product was obsd., as measured by ICP-MS anal. [on SciFinder(R)]

KW - glucose palladium nanoparticle catalyst Suzuki Miyaura cross coupling

U2 - 10.1021/sc400410v

DO - 10.1021/sc400410v

M3 - Article

SN - 2168-0485

VL - 2

SP - 500

EP - 505

JO - ACS Sustainable Chemisty and Engineering

JF - ACS Sustainable Chemisty and Engineering

IS - 3

ER -

Glucose-Derived Palladium(0) Nanoparticles as in Situ-Formed Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Isopropanol.

Abstract

Bibliographical note

Keywords

UN SDGs

Access to Document

Fingerprint

Cite this