Geometrical variety in heptanuclear clusters of osmium; Crystal structures of [Os7H2(CO)21] and [Os7H 2(CO)22]

Brian F. G. Johnson; Jack Lewis; Mary McPartlin; Jill Morris; Gregory L. Powell; Paul R. Raithby; Maria D. Vargas

doi:10.1039/C39860000429

Geometrical variety in heptanuclear clusters of osmium; Crystal structures of [Os₇H₂(CO)₂₁] and [Os₇H ₂(CO)₂₂]

Brian F. G. Johnson, Jack Lewis, Mary McPartlin, Jill Morris, Gregory L. Powell, Paul R. Raithby, Maria D. Vargas

Research output: Contribution to journal › Article › peer-review

Abstract

Treatment of the cluster [Os₆(CO)₁₈] with Me ₃NO in the presence of [OsH₂(CO)₄] affords the new heptanuclear cluster compounds [Os₇H₂(CO) ₂₂] (1) and [Os₇H₂(CO)₂₁] (2), and the known compound [Os₇H₂(CO)₂₀] (3), which have been shown by X-ray diffraction studies to exhibit novel metal geometries; these clusters are interconvertible by stepwise loss (and, in one case, gain) of CO.

Original language	English
Pages (from-to)	429-431
Number of pages	3
Journal	Journal of the Chemical Society (Resumed)
Issue number	6
DOIs	https://doi.org/10.1039/C39860000429
Publication status	Published - 31 Dec 1986

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39860000429

Cite this

@article{049a0760615848cdb65ce2a62bae29a5,

title = "Geometrical variety in heptanuclear clusters of osmium; Crystal structures of [Os7H2(CO)21] and [Os7H 2(CO)22]",

abstract = "Treatment of the cluster [Os6(CO)18] with Me 3NO in the presence of [OsH2(CO)4] affords the new heptanuclear cluster compounds [Os7H2(CO) 22] (1) and [Os7H2(CO)21] (2), and the known compound [Os7H2(CO)20] (3), which have been shown by X-ray diffraction studies to exhibit novel metal geometries; these clusters are interconvertible by stepwise loss (and, in one case, gain) of CO.",

author = "Johnson, {Brian F. G.} and Jack Lewis and Mary McPartlin and Jill Morris and Powell, {Gregory L.} and Raithby, {Paul R.} and Vargas, {Maria D.}",

year = "1986",

month = dec,

day = "31",

doi = "10.1039/C39860000429",

language = "English",

pages = "429--431",

journal = "Journal of the Chemical Society (Resumed)",

issn = "0022-4936",

publisher = "Chemical Society",

number = "6",

}

TY - JOUR

T1 - Geometrical variety in heptanuclear clusters of osmium; Crystal structures of [Os7H2(CO)21] and [Os7H 2(CO)22]

AU - Johnson, Brian F. G.

AU - Lewis, Jack

AU - McPartlin, Mary

AU - Morris, Jill

AU - Powell, Gregory L.

AU - Raithby, Paul R.

AU - Vargas, Maria D.

PY - 1986/12/31

Y1 - 1986/12/31

N2 - Treatment of the cluster [Os6(CO)18] with Me 3NO in the presence of [OsH2(CO)4] affords the new heptanuclear cluster compounds [Os7H2(CO) 22] (1) and [Os7H2(CO)21] (2), and the known compound [Os7H2(CO)20] (3), which have been shown by X-ray diffraction studies to exhibit novel metal geometries; these clusters are interconvertible by stepwise loss (and, in one case, gain) of CO.

AB - Treatment of the cluster [Os6(CO)18] with Me 3NO in the presence of [OsH2(CO)4] affords the new heptanuclear cluster compounds [Os7H2(CO) 22] (1) and [Os7H2(CO)21] (2), and the known compound [Os7H2(CO)20] (3), which have been shown by X-ray diffraction studies to exhibit novel metal geometries; these clusters are interconvertible by stepwise loss (and, in one case, gain) of CO.

UR - http://www.scopus.com/inward/record.url?scp=37049070774&partnerID=8YFLogxK

U2 - 10.1039/C39860000429

DO - 10.1039/C39860000429

M3 - Article

AN - SCOPUS:37049070774

SN - 0022-4936

SP - 429

EP - 431

JO - Journal of the Chemical Society (Resumed)

JF - Journal of the Chemical Society (Resumed)

IS - 6

ER -

Geometrical variety in heptanuclear clusters of osmium; Crystal structures of [Os₇H₂(CO)₂₁] and [Os₇H ₂(CO)₂₂]

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this