Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN

C S Clarke; Sofia I Pascu; J M Rawson

doi:10.1039/b403430a

Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN

C S Clarke
, Sofia I Pascu
, J M Rawson

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (SciVal)

Abstract

A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75% of the anticipated number of contacts are observed.

Original language	English
Pages (from-to)	79-82
Number of pages	4
Journal	CrystEngComm
Volume	6
DOIs	https://doi.org/10.1039/b403430a
Publication status	Published - 2004

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title = "Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN",

abstract = "A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75\% of the anticipated number of contacts are observed.",

author = "Clarke, \{C S\} and Pascu, \{Sofia I\} and Rawson, \{J M\}",

year = "2004",

doi = "10.1039/b403430a",

language = "English",

volume = "6",

pages = "79--82",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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T1 - Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN

AU - Clarke, C S

AU - Pascu, Sofia I

AU - Rawson, J M

PY - 2004

Y1 - 2004

N2 - A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75% of the anticipated number of contacts are observed.

AB - A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75% of the anticipated number of contacts are observed.

UR - http://dx.doi.org/10.1039/b403430a

U2 - 10.1039/b403430a

DO - 10.1039/b403430a

M3 - Article

SN - 1466-8033

VL - 6

SP - 79

EP - 82

JO - CrystEngComm

JF - CrystEngComm

ER -

Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN

Abstract

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