Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN

C S Clarke, Sofia I Pascu, J M Rawson

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75% of the anticipated number of contacts are observed.
Original languageEnglish
Pages (from-to)79-82
Number of pages4
JournalCrystEngComm
Volume6
DOIs
Publication statusPublished - 2004

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Cite this

Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN. / Clarke, C S; Pascu, Sofia I; Rawson, J M.

In: CrystEngComm, Vol. 6, 2004, p. 79-82.

Research output: Contribution to journalArticle

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abstract = "A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75{\%} of the anticipated number of contacts are observed.",
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