Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

William J. Gee; Laura K. Cadman; Harina Amer Hamzah; Mary F. Mahon; Paul R. Raithby; Andrew D. Burrows

doi:10.1021/acs.inorgchem.6b01917

Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

William J. Gee, Laura K. Cadman, Harina Amer Hamzah, Mary F. Mahon, Paul R. Raithby, Andrew D. Burrows

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Abstract

The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

Original language	English
Pages (from-to)	10839-10842
Journal	Inorganic Chemistry
Volume	55
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01917
Publication status	Published - 7 Nov 2016

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10.1021/acs.inorgchem.6b01917

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This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see DOI: 10.1021/acs.inorgchem.6b01917
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title = "Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification",

abstract = "The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.",

author = "Gee, \{William J.\} and Cadman, \{Laura K.\} and \{Amer Hamzah\}, Harina and Mahon, \{Mary F.\} and Raithby, \{Paul R.\} and Burrows, \{Andrew D.\}",

year = "2016",

month = nov,

day = "7",

doi = "10.1021/acs.inorgchem.6b01917",

language = "English",

volume = "55",

pages = "10839--10842",

journal = "Inorganic Chemistry",

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T1 - Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

AU - Gee, William J.

AU - Cadman, Laura K.

AU - Amer Hamzah, Harina

AU - Mahon, Mary F.

AU - Raithby, Paul R.

AU - Burrows, Andrew D.

PY - 2016/11/7

Y1 - 2016/11/7

N2 - The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

AB - The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

UR - http://dx.doi.org/10.1021/acs.inorgchem.6b01917

UR - https://www.scopus.com/pages/publications/84994676979

U2 - 10.1021/acs.inorgchem.6b01917

DO - 10.1021/acs.inorgchem.6b01917

M3 - Article

SN - 0020-1669

VL - 55

SP - 10839

EP - 10842

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

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Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly

Andy Burrows

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

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Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly

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Andy Burrows

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MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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