Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification

William J. Gee, Laura K. Cadman, Harina Amer Hamzah, Mary F. Mahon, Paul R. Raithby, Andrew D. Burrows

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Abstract

The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.
Original languageEnglish
Pages (from-to)10839-10842
JournalInorganic Chemistry
Volume55
Issue number21
DOIs
Publication statusPublished - 7 Nov 2016

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Bearings (structural)
Amines
amines
Metals
Atoms
metals
crystallinity
solid state
products
atoms
diketene

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Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification. / Gee, William J.; Cadman, Laura K.; Amer Hamzah, Harina; Mahon, Mary F.; Raithby, Paul R.; Burrows, Andrew D.

In: Inorganic Chemistry, Vol. 55, No. 21, 07.11.2016, p. 10839-10842.

Research output: Contribution to journalArticle

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