Projects per year
Abstract
The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.
Original language | English |
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Pages (from-to) | 10839-10842 |
Journal | Inorganic Chemistry |
Volume | 55 |
Issue number | 21 |
DOIs | |
Publication status | Published - 7 Nov 2016 |
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Dive into the research topics of 'Furnishing amine-functionalized metal-organic-frameworks with the β-amidoketone group by post-synthetic modification'. Together they form a unique fingerprint.Projects
- 1 Finished
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Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly
Raithby, P. (PI), Burrows, A. (CoI), Lewis, D. (CoI), Marken, F. (CoI), Parker, S. (CoI), Walsh, A. (CoI) & Wilson, C. (CoI)
Engineering and Physical Sciences Research Council
1/11/12 → 30/04/18
Project: Research council
Profiles
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Andrew Burrows
- Department of Chemistry - Professor
- Centre for Sustainable Chemical Technologies (CSCT)
- Faculty of Science - Associate Dean (Education)
- Centre for Integrated Materials, Processes & Structures (IMPS)
- Institute of Sustainability and Climate Change
Person: Research & Teaching, Affiliate staff
Equipment
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MC2- Nuclear Magnetic Resonance (NMR)
Material and Chemical Characterisation (MC2)Facility/equipment: Technology type
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MC2- X-ray diffraction (XRD)
Material and Chemical Characterisation (MC2)Facility/equipment: Technology type