Fragmentation of an imido tin(II) cubane; syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions

Robert E. Allan; Michael A. Beswick; Natalie L. Cromhout; Michael A. Paver; Paul R. Raithby; Alexander Steiner; Mark Trevithick; Dominic S. Wright

doi:10.1039/cc9960001501

Fragmentation of an imido tin(II) cubane; syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions

Robert E. Allan, Michael A. Beswick, Natalie L. Cromhout, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Mark Trevithick, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

47 Citations (SciVal)

Abstract

The reactions of the imido tin(II) cubane [SnNBu^t]₄ with 3 equiv. of [C₁₀H₇NHLi] (C₁₀H₇ = 1-naphthyl) and 6 equiv. of [C₆H₁₁PHLi] (C₆H₁₁ = cyclohexyl) produce [Li(thf)₄]⁺[(Bu^tN)(C₁₀H ₇N)₃Sn₃Li·thf] ^-·thf·PhMe 1 and [{Sn₂(PC₆H₁₁)₃}₂Li ₄·4thf]·2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.

Original language	English
Pages (from-to)	1501-1502
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/cc9960001501
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Fragmentation of an imido tin(II) cubane; syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions",

abstract = "The reactions of the imido tin(II) cubane [SnNBut]4 with 3 equiv. of [C10H7NHLi] (C10H7 = 1-naphthyl) and 6 equiv. of [C6H11PHLi] (C6H11 = cyclohexyl) produce [Li(thf)4]+[(ButN)(C10H 7N)3Sn3Li·thf] -·thf·PhMe 1 and [\{Sn2(PC6H11)3\}2Li 4·4thf]·2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.",

author = "Allan, \{Robert E.\} and Beswick, \{Michael A.\} and Cromhout, \{Natalie L.\} and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Alexander Steiner and Mark Trevithick and Wright, \{Dominic S.\}",

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doi = "10.1039/cc9960001501",

language = "English",

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T1 - Fragmentation of an imido tin(II) cubane; syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions

AU - Allan, Robert E.

AU - Beswick, Michael A.

AU - Cromhout, Natalie L.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Trevithick, Mark

AU - Wright, Dominic S.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The reactions of the imido tin(II) cubane [SnNBut]4 with 3 equiv. of [C10H7NHLi] (C10H7 = 1-naphthyl) and 6 equiv. of [C6H11PHLi] (C6H11 = cyclohexyl) produce [Li(thf)4]+[(ButN)(C10H 7N)3Sn3Li·thf] -·thf·PhMe 1 and [{Sn2(PC6H11)3}2Li 4·4thf]·2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.

AB - The reactions of the imido tin(II) cubane [SnNBut]4 with 3 equiv. of [C10H7NHLi] (C10H7 = 1-naphthyl) and 6 equiv. of [C6H11PHLi] (C6H11 = cyclohexyl) produce [Li(thf)4]+[(ButN)(C10H 7N)3Sn3Li·thf] -·thf·PhMe 1 and [{Sn2(PC6H11)3}2Li 4·4thf]·2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.

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DO - 10.1039/cc9960001501

M3 - Article

AN - SCOPUS:0002616844

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Fragmentation of an imido tin(II) cubane; syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions

Abstract

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