Abstract
The reactions of the imido tin(II) cubane [SnNBut]4 with 3 equiv. of [C10H7NHLi] (C10H7 = 1-naphthyl) and 6 equiv. of [C6H11PHLi] (C6H11 = cyclohexyl) produce [Li(thf)4]+[(ButN)(C10H 7N)3Sn3Li·thf] -·thf·PhMe 1 and [{Sn2(PC6H11)3}2Li 4·4thf]·2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.
Original language | English |
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Pages (from-to) | 1501-1502 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 13 |
DOIs | |
Publication status | Published - 1 Jan 1996 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry