Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

Robert Chapman, Molly Francis, Ruth Lawrence, Joshua Tibbetts, Steven Bull

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.
Original languageEnglish
Pages (from-to)6442-6452
Number of pages11
JournalTetrahedron
Volume74
Issue number44
Early online date11 Sep 2018
DOIs
Publication statusPublished - 1 Nov 2018

Cite this

Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols. / Chapman, Robert; Francis, Molly; Lawrence, Ruth; Tibbetts, Joshua; Bull, Steven.

In: Tetrahedron, Vol. 74, No. 44, 01.11.2018, p. 6442-6452.

Research output: Contribution to journalArticle

@article{09eae4f9ffcf40bebda36fc558d3f0a5,
title = "Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols",
abstract = "Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.",
author = "Robert Chapman and Molly Francis and Ruth Lawrence and Joshua Tibbetts and Steven Bull",
year = "2018",
month = "11",
day = "1",
doi = "10.1016/j.tet.2018.09.014",
language = "English",
volume = "74",
pages = "6442--6452",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier",
number = "44",

}

TY - JOUR

T1 - Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

AU - Chapman, Robert

AU - Francis, Molly

AU - Lawrence, Ruth

AU - Tibbetts, Joshua

AU - Bull, Steven

PY - 2018/11/1

Y1 - 2018/11/1

N2 - Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.

AB - Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.

U2 - 10.1016/j.tet.2018.09.014

DO - 10.1016/j.tet.2018.09.014

M3 - Article

VL - 74

SP - 6442

EP - 6452

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 44

ER -