Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

Robert Chapman; Molly Francis; Ruth Lawrence; Joshua Tibbetts; Steven Bull

doi:10.1016/j.tet.2018.09.014

Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

Robert Chapman, Molly Francis, Ruth Lawrence, Joshua Tibbetts, Steven Bull

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Abstract

Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.

Original language	English
Pages (from-to)	6442-6452
Number of pages	11
Journal	Tetrahedron
Volume	74
Issue number	44
Early online date	11 Sept 2018
DOIs	https://doi.org/10.1016/j.tet.2018.09.014
Publication status	Published - 1 Nov 2018

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10.1016/j.tet.2018.09.014

O_formylation_and_acylation_Tetrahedron_JDT_corrections_300818.pdfAccepted author manuscript, 1.09 MBLicence: CC BY-NC-ND

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title = "Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols",

abstract = "Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.",

author = "Robert Chapman and Molly Francis and Ruth Lawrence and Joshua Tibbetts and Steven Bull",

year = "2018",

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doi = "10.1016/j.tet.2018.09.014",

language = "English",

volume = "74",

pages = "6442--6452",

journal = "Tetrahedron",

issn = "0040-4020",

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T1 - Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

AU - Chapman, Robert

AU - Francis, Molly

AU - Lawrence, Ruth

AU - Tibbetts, Joshua

AU - Bull, Steven

PY - 2018/11/1

Y1 - 2018/11/1

N2 - Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.

AB - Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.

U2 - 10.1016/j.tet.2018.09.014

DO - 10.1016/j.tet.2018.09.014

M3 - Article

SN - 0040-4020

VL - 74

SP - 6442

EP - 6452

JO - Tetrahedron

JF - Tetrahedron

IS - 44

ER -

Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

Abstract

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Avance 300 MHz Nuclear Magnetic Resonance (NMR) Spectrometer (1South)

Electrospray Time-of-Flight Mass Spectrometer (Open-Access)

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