Formation of low density hydrous iron oxide via conformal transformation of MIL-53(Fe)

Talha J. Pirzada; S A MacGregor; Safeer Ahmed; Karen J. Edler; Harina Amer Hamzah; Dongmei Jiang; Andrew D. Burrows; John M. Mitchels; Ibrahim A. I. Hassan; Jonathan E. Halls; Frank Marken

doi:10.1039/c3cc46655h

Formation of low density hydrous iron oxide via conformal transformation of MIL-53(Fe)

Talha J. Pirzada, S A MacGregor, Safeer Ahmed, Karen J. Edler, Harina Amer Hamzah, Dongmei Jiang, Andrew D. Burrows, John M. Mitchels, Ibrahim A. I. Hassan, Jonathan E. Halls, Frank Marken

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Hydrous iron oxide materials with a predefined shape, photo-electrochemical activity, low density (estimated to be 0.32 g cm−3), and high fractal porosity (BET ca. 117 m2 g−1) are formed via internal hydrolytic transformation of the crystalline metal–organic framework MIL-53(Fe) in dilute aqueous hydroxide.

Original language	English
Pages (from-to)	10593-10595
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	90
Early online date	4 Oct 2013
DOIs	https://doi.org/10.1039/c3cc46655h
Publication status	Published - 21 Nov 2013

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10.1039/c3cc46655h

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2 Finished

Nano-Integration of Metal-Organic Frameworks and Catalysis for the Uptake and Utilisation of CO2
Marken, F., Burrows, A., Cameron, P., Edler, K., Jones, M., Pascu, S. & Raithby, P.
Engineering and Physical Sciences Research Council
1/05/10 → 14/02/14
Project: Research council
SAXSESS - SMALL ANGLE X-RAY SCATTERING SYSTEM FOR MATERIALS CHEMISTRY
Edler, K., Jones, '., Marken, F., Price, G., Roser, S. & Weller, A.
Engineering and Physical Sciences Research Council
31/01/07 → 30/01/09
Project: Research council

Cite this

Formation of low density hydrous iron oxide via conformal transformation of MIL-53(Fe). / Pirzada, Talha J.; MacGregor, S A; Ahmed, Safeer; Edler, Karen J.; Hamzah, Harina Amer; Jiang, Dongmei; Burrows, Andrew D.; Mitchels, John M.; Hassan, Ibrahim A. I.; Halls, Jonathan E.; Marken, Frank.

In: Chemical Communications, Vol. 49, No. 90, 21.11.2013, p. 10593-10595.

Research output: Contribution to journal › Article › peer-review

Pirzada, Talha J. ; MacGregor, S A ; Ahmed, Safeer ; Edler, Karen J. ; Hamzah, Harina Amer ; Jiang, Dongmei ; Burrows, Andrew D. ; Mitchels, John M. ; Hassan, Ibrahim A. I. ; Halls, Jonathan E. ; Marken, Frank. / Formation of low density hydrous iron oxide via conformal transformation of MIL-53(Fe). In: Chemical Communications. 2013 ; Vol. 49, No. 90. pp. 10593-10595.

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abstract = "Hydrous iron oxide materials with a predefined shape, photo-electrochemical activity, low density (estimated to be 0.32 g cm−3), and high fractal porosity (BET ca. 117 m2 g−1) are formed via internal hydrolytic transformation of the crystalline metal–organic framework MIL-53(Fe) in dilute aqueous hydroxide.",

author = "Pirzada, {Talha J.} and MacGregor, {S A} and Safeer Ahmed and Edler, {Karen J.} and Hamzah, {Harina Amer} and Dongmei Jiang and Burrows, {Andrew D.} and Mitchels, {John M.} and Hassan, {Ibrahim A. I.} and Halls, {Jonathan E.} and Frank Marken",

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AU - Pirzada, Talha J.

AU - MacGregor, S A

AU - Ahmed, Safeer

AU - Edler, Karen J.

AU - Hamzah, Harina Amer

AU - Jiang, Dongmei

AU - Burrows, Andrew D.

AU - Mitchels, John M.

AU - Hassan, Ibrahim A. I.

AU - Halls, Jonathan E.

AU - Marken, Frank

PY - 2013/11/21

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N2 - Hydrous iron oxide materials with a predefined shape, photo-electrochemical activity, low density (estimated to be 0.32 g cm−3), and high fractal porosity (BET ca. 117 m2 g−1) are formed via internal hydrolytic transformation of the crystalline metal–organic framework MIL-53(Fe) in dilute aqueous hydroxide.

AB - Hydrous iron oxide materials with a predefined shape, photo-electrochemical activity, low density (estimated to be 0.32 g cm−3), and high fractal porosity (BET ca. 117 m2 g−1) are formed via internal hydrolytic transformation of the crystalline metal–organic framework MIL-53(Fe) in dilute aqueous hydroxide.

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Formation of low density hydrous iron oxide via conformal transformation of MIL-53(Fe)

Abstract

Access to Document

Nano-Integration of Metal-Organic Frameworks and Catalysis for the Uptake and Utilisation of CO2

SAXSESS - SMALL ANGLE X-RAY SCATTERING SYSTEM FOR MATERIALS CHEMISTRY

Cite this