Formation of carbene and cyclopentadienyl ligands from phenylacetylene via oligomerisation and C≡C bond scission at a mixed-metal W-Co centre

John E. Davies; Martin J. Mays; Paul R. Raithby; Koshala Sarveswaran; Gregory A. Solan

doi:10.1039/b003296o

Formation of carbene and cyclopentadienyl ligands from phenylacetylene via oligomerisation and C≡C bond scission at a mixed-metal W-Co centre

John E. Davies, Martin J. Mays, Paul R. Raithby, Koshala Sarveswaran, Gregory A. Solan

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The 1,2,4-triphenylcyclopentadienyl ligand and the CHR carbene ligand, bound respectively to the Co and W atoms in [(η⁵-C₅H₅)W{μ- CBu(t)CC(CO₂Me)=C(CO₂Me)CH}(μPPh₂)Co(η⁵-C₅Ph₃H₂)], are derived from the oligomerisation and cleavage of three molecules of phenylacetylene in the reaction of [(OC)(η⁵-C₅H₅)W{η-C(CO₂Me)CC(C≡CBu(t))(OMe)O}(μ- PPh₂)Co(CO)₂] with this acetylene.

Original language	English
Pages (from-to)	1313-1314
Number of pages	2
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b003296o
Publication status	Published - 21 Jul 2000

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Formation of carbene and cyclopentadienyl ligands from phenylacetylene via oligomerisation and C≡C bond scission at a mixed-metal W-Co centre",

abstract = "The 1,2,4-triphenylcyclopentadienyl ligand and the CHR carbene ligand, bound respectively to the Co and W atoms in [(η5-C5H5)W{μ- CBu(t)CC(CO2Me)=C(CO2Me)CH}(μPPh2)Co(η5-C5Ph3H2)], are derived from the oligomerisation and cleavage of three molecules of phenylacetylene in the reaction of [(OC)(η5-C5H5)W{η-C(CO2Me)CC(C≡CBu(t))(OMe)O}(μ- PPh2)Co(CO)2] with this acetylene.",

author = "Davies, {John E.} and Mays, {Martin J.} and Raithby, {Paul R.} and Koshala Sarveswaran and Solan, {Gregory A.}",

year = "2000",

month = jul,

day = "21",

doi = "10.1039/b003296o",

language = "English",

pages = "1313--1314",

journal = "Chemical communications (Cambridge, England)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "14",

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T1 - Formation of carbene and cyclopentadienyl ligands from phenylacetylene via oligomerisation and C≡C bond scission at a mixed-metal W-Co centre

AU - Davies, John E.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Sarveswaran, Koshala

AU - Solan, Gregory A.

PY - 2000/7/21

Y1 - 2000/7/21

N2 - The 1,2,4-triphenylcyclopentadienyl ligand and the CHR carbene ligand, bound respectively to the Co and W atoms in [(η5-C5H5)W{μ- CBu(t)CC(CO2Me)=C(CO2Me)CH}(μPPh2)Co(η5-C5Ph3H2)], are derived from the oligomerisation and cleavage of three molecules of phenylacetylene in the reaction of [(OC)(η5-C5H5)W{η-C(CO2Me)CC(C≡CBu(t))(OMe)O}(μ- PPh2)Co(CO)2] with this acetylene.

AB - The 1,2,4-triphenylcyclopentadienyl ligand and the CHR carbene ligand, bound respectively to the Co and W atoms in [(η5-C5H5)W{μ- CBu(t)CC(CO2Me)=C(CO2Me)CH}(μPPh2)Co(η5-C5Ph3H2)], are derived from the oligomerisation and cleavage of three molecules of phenylacetylene in the reaction of [(OC)(η5-C5H5)W{η-C(CO2Me)CC(C≡CBu(t))(OMe)O}(μ- PPh2)Co(CO)2] with this acetylene.

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DO - 10.1039/b003296o

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EP - 1314

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

SN - 1359-7345

IS - 14

ER -

Formation of carbene and cyclopentadienyl ligands from phenylacetylene via oligomerisation and C≡C bond scission at a mixed-metal W-Co centre

Abstract

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