First structural characterisation of a 2,1,12-MC2B9 metallacarborane, [2,2,2-(NMe2)3-closo-2,1,12-TaC2B 9H11]. Trends in boron NMR shifts on replacing a {BH} vertex with a metal {MLn} vertex in icosahedral carboranes

Andrci S. Batsanov, Pauline A. Eva, Mark A. Fox, Judith A.K. Howard, Andrew K. Hughes, Andrew L. Johnson, Aileen M. Martin, Ken Wade

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Dive into the research topics of 'First structural characterisation of a 2,1,12-MC<sub>2</sub>B<sub>9</sub> metallacarborane, [2,2,2-(NMe<sub>2</sub>)<sub>3</sub>-closo-2,1,12-TaC<sub>2</sub>B <sub>9</sub>H<sub>11</sub>]. Trends in boron NMR shifts on replacing a {BH} vertex with a metal {ML<sub>n</sub>} vertex in icosahedral carboranes'. Together they form a unique fingerprint.

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