Abstract
Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.
Original language | English |
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Pages (from-to) | 10219-10222 |
Number of pages | 4 |
Journal | Dalton Transactions |
Volume | 2009 |
Issue number | 46 |
Early online date | 26 Oct 2009 |
DOIs | |
Publication status | Published - 2009 |