First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Antoine Buchard, Audrey Auffrant, Louis Ricard, Xavier F. Le Goff, Rachel H. Platel, Charlotte K. Williams, Pascal Le Floch

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.
Original languageEnglish
Pages (from-to)10219-10222
Number of pages4
JournalDalton Transactions
Volume2009
Issue number46
Early online date26 Oct 2009
DOIs
Publication statusPublished - 2009

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Neodymium
Deprotonation
Ligands
X rays
carbene

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Buchard, A., Auffrant, A., Ricard, L., Le Goff, X. F., Platel, R. H., Williams, C. K., & Le Floch, P. (2009). First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands. Dalton Transactions, 2009(46), 10219-10222. https://doi.org/10.1039/B918971H

First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands. / Buchard, Antoine; Auffrant, Audrey; Ricard, Louis; Le Goff, Xavier F.; Platel, Rachel H.; Williams, Charlotte K.; Le Floch, Pascal.

In: Dalton Transactions, Vol. 2009, No. 46, 2009, p. 10219-10222.

Research output: Contribution to journalArticle

Buchard, A, Auffrant, A, Ricard, L, Le Goff, XF, Platel, RH, Williams, CK & Le Floch, P 2009, 'First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands', Dalton Transactions, vol. 2009, no. 46, pp. 10219-10222. https://doi.org/10.1039/B918971H
Buchard A, Auffrant A, Ricard L, Le Goff XF, Platel RH, Williams CK et al. First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands. Dalton Transactions. 2009;2009(46):10219-10222. https://doi.org/10.1039/B918971H
Buchard, Antoine ; Auffrant, Audrey ; Ricard, Louis ; Le Goff, Xavier F. ; Platel, Rachel H. ; Williams, Charlotte K. ; Le Floch, Pascal. / First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands. In: Dalton Transactions. 2009 ; Vol. 2009, No. 46. pp. 10219-10222.
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