First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Antoine Buchard, Audrey Auffrant, Louis Ricard, Xavier F. Le Goff, Rachel H. Platel, Charlotte K. Williams, Pascal Le Floch

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.
Original languageEnglish
Pages (from-to)10219-10222
Number of pages4
JournalDalton Transactions
Volume2009
Issue number46
Early online date26 Oct 2009
DOIs
Publication statusPublished - 2009

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