Abstract
We generalize the simplest kinetically constrained model of a glass-forming liquid by softening kinetic constraints, allowing them to be violated with a small rate. We demonstrate that this model supports a first-order dynamical (space-time) phase transition between active (fluid) and inactive (glass) phases. The first-order phase boundary in this softened model ends in a finite-temperature dynamical critical point, which may be present in natural systems. In this case, the glass phase has a very large but finite relaxation time. We discuss links between the dynamical critical point and quantum phase transitions, showing that dynamical phase transitions in d dimensions map to quantum transitions in the same dimension, and hence to classical thermodynamic phase transitions in d + 1 dimensions.
| Original language | English |
|---|---|
| Pages (from-to) | 12793-12798 |
| Number of pages | 6 |
| Journal | Proceedings of the National Academy of Sciences of the United States of America |
| Volume | 107 |
| Issue number | 29 |
| Early online date | 1 Jul 2010 |
| DOIs | |
| Publication status | Published - 20 Jul 2010 |
Keywords
- critical behavior
- supercooled liquids