TY - JOUR
T1 - Faraday rotation and its dispersion in the visible region for saturated organic liquids
AU - Vandendriessche, Stefaan
AU - Valev, Ventsislav K.
AU - Verbiest, Thierry
PY - 2012/2/14
Y1 - 2012/2/14
N2 - Faraday rotation and its dispersion have been measured and calculated in the 400-800 nm wavelength range for a set of saturated organic liquids. The resulting Verdet constants are fitted and trends are analyzed. Comparisons are made to both the polarizability and diamagnetic susceptibility. The data are applied to a connectivity index model, allowing prediction of Verdet constants of aliphatic organic liquids from 400 to 800 nm. The observed correlations and connectivity model improve the understanding of Faraday rotation in diamagnetic materials, allowing for future optimization.
AB - Faraday rotation and its dispersion have been measured and calculated in the 400-800 nm wavelength range for a set of saturated organic liquids. The resulting Verdet constants are fitted and trends are analyzed. Comparisons are made to both the polarizability and diamagnetic susceptibility. The data are applied to a connectivity index model, allowing prediction of Verdet constants of aliphatic organic liquids from 400 to 800 nm. The observed correlations and connectivity model improve the understanding of Faraday rotation in diamagnetic materials, allowing for future optimization.
UR - http://www.scopus.com/inward/record.url?scp=84856734752&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1039/c2cp23311h
U2 - 10.1039/c2cp23311h
DO - 10.1039/c2cp23311h
M3 - Article
AN - SCOPUS:84856734752
SN - 1463-9076
VL - 14
SP - 1860
EP - 1864
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
IS - 6
ER -