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A facile in situ nanoparticle seeding method is reported to prepare MIL-101(Cr) films on alumina supports. The in situ seeding of MIL-101(Cr) nanoparticles was promoted by use of dimethylacetamide (DMA). The generality of this approach is further demonstrated for Cu 3(btc) 2 films by using a (poly)acrylate promoter.
Jiang, D., Burrows, A. D., Jaber, R., & Edler, K. J. (2012). Facile synthesis of metal-organic framework films via in situ seeding of nanoparticles. Chemical Communications, 48(41), 4965-4967. https://doi.org/10.1039/c2cc31079a