Facile synthesis of crack-free metal-organic framework films on alumina by a dip-coating route in the presence of polyethylenimine

D. Jiang; A.D. Burrows; Y. Xiong; K.J. Edler

doi:10.1039/c3ta10766c

Facile synthesis of crack-free metal-organic framework films on alumina by a dip-coating route in the presence of polyethylenimine

D. Jiang, A.D. Burrows, Y. Xiong, K.J. Edler

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Abstract

A facile polyethylenimine (PEI)-assisted dip-coating method allows crack-free films of MIL-101(Cr) and MIL-101(Cr)-NH₂ to be prepared on alumina supports. The presence of PEI enhances the selectivity of the films for CO₂ with respect to N₂. The film surfaces can be made hydrophobic by further dip-coating with an aliphatic monocarboxylic acid.

Original language	English
Pages (from-to)	5497-5500
Number of pages	4
Journal	Journal of Materials Chemistry A
Volume	1
Issue number	18
Early online date	5 Apr 2013
DOIs	https://doi.org/10.1039/c3ta10766c
Publication status	Published - 2013

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10.1039/c3ta10766c

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title = "Facile synthesis of crack-free metal-organic framework films on alumina by a dip-coating route in the presence of polyethylenimine",

abstract = "A facile polyethylenimine (PEI)-assisted dip-coating method allows crack-free films of MIL-101(Cr) and MIL-101(Cr)-NH2 to be prepared on alumina supports. The presence of PEI enhances the selectivity of the films for CO2 with respect to N2. The film surfaces can be made hydrophobic by further dip-coating with an aliphatic monocarboxylic acid.",

author = "D. Jiang and A.D. Burrows and Y. Xiong and K.J. Edler",

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AU - Edler, K.J.

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AB - A facile polyethylenimine (PEI)-assisted dip-coating method allows crack-free films of MIL-101(Cr) and MIL-101(Cr)-NH2 to be prepared on alumina supports. The presence of PEI enhances the selectivity of the films for CO2 with respect to N2. The film surfaces can be made hydrophobic by further dip-coating with an aliphatic monocarboxylic acid.

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Facile synthesis of crack-free metal-organic framework films on alumina by a dip-coating route in the presence of polyethylenimine

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Nano-Integration of Metal-Organic Frameworks and Catalysis for the Uptake and Utilisation of CO2

RESPONSIVE MEMBRANES FROM POLYMER-SURFACTANT FILMS

MC2-Electron Microscopy (EM)

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Facile synthesis of crack-free metal-organic framework films on alumina by a dip-coating route in the presence of polyethylenimine

Abstract

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Fingerprint

Projects

Nano-Integration of Metal-Organic Frameworks and Catalysis for the Uptake and Utilisation of CO2

RESPONSIVE MEMBRANES FROM POLYMER-SURFACTANT FILMS

Equipment

MC2-Electron Microscopy (EM)

Cite this