Projects per year
Reactions between magnesium 1,4-dihydropyridide or 1,2-dihydro-iso-quinolide derivatives and carbodiimides, RN=C=NR, generally result in Mg-N insertion and formation of guanidinate complexes. More sterically perturbed systems with N-aryl carbodiimide substitution, however, follow a divergent course of reaction initiating heterocyclic ring contraction and pyrrolide formation under unprecedentedly mild conditions.
FingerprintDive into the research topics of 'Facile kinetic induction of a dihydropyridide to pyrrolide ring contraction'. Together they form a unique fingerprint.
- 1 Finished
23/05/11 → 31/03/15
Project: Research council