Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 5925-5928 |
| Journal | Dalton Transactions |
| Volume | 45 |
| Issue number | 14 |
| Early online date | 19 Aug 2015 |
| DOIs | |
| Publication status | Published - 14 Apr 2016 |
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Facile kinetic induction of a dihydropyridide to pyrrolide ring contraction. / Carbery, David R.; Hill, Michael S.; Mahon, Mary F.; Weetman, Catherine.
In: Dalton Transactions , Vol. 45, No. 14, 14.04.2016, p. 5925-5928.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Facile kinetic induction of a dihydropyridide to pyrrolide ring contraction
AU - Carbery, David R.
AU - Hill, Michael S.
AU - Mahon, Mary F.
AU - Weetman, Catherine
PY - 2016/4/14
Y1 - 2016/4/14
N2 - Reactions between magnesium 1,4-dihydropyridide or 1,2-dihydro-iso-quinolide derivatives and carbodiimides, RN=C=NR, generally result in Mg-N insertion and formation of guanidinate complexes. More sterically perturbed systems with N-aryl carbodiimide substitution, however, follow a divergent course of reaction initiating heterocyclic ring contraction and pyrrolide formation under unprecedentedly mild conditions.
AB - Reactions between magnesium 1,4-dihydropyridide or 1,2-dihydro-iso-quinolide derivatives and carbodiimides, RN=C=NR, generally result in Mg-N insertion and formation of guanidinate complexes. More sterically perturbed systems with N-aryl carbodiimide substitution, however, follow a divergent course of reaction initiating heterocyclic ring contraction and pyrrolide formation under unprecedentedly mild conditions.
UR - http://dx.doi.org/10.1039/C5DT02887F
U2 - 10.1039/C5DT02887F
DO - 10.1039/C5DT02887F
M3 - Article
VL - 45
SP - 5925
EP - 5928
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 14
ER -