Projects per year
DFT calculations on palladium(II) methyl complexes incorporating P/N ligands demonstrate that CO activation in the presence of competing ligands, such as CH3CN or C2H4, occurs through an associative mechanism involving CO/ligand exchange, followed by migratory insertion of CO into the Pd-Me bond. Recent investigations into the PdII coordination of CO and C2H4 and their subsequent insertion into the Pd-Me bonds of complexes of the type [PdMe(iminophosphine)(NCMe)]+ are reported.
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- 1 Finished
1/05/10 → 14/02/14
Project: Research council