(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

M D Jones, F A A Paz, J E Davies, B F G Johnson

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.
Original languageEnglish
Pages (from-to)M105-M107
JournalActa Crystallographica Section E-Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

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