(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

M D Jones, F A A Paz, J E Davies, B F G Johnson

Research output: Contribution to journalArticle

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Abstract

The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.
LanguageEnglish
PagesM105-M107
JournalActa Crystallographica Section E-Structure Reports Online
Volume59
DOIs
StatusPublished - 2003

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Palladium
Chelation
Anions
Cations
palladium
Hydrogen
Negative ions
Positive ions
Metals
Ligands
anions
cations
ligands
Geometry
hydrogen
geometry
metals
pyrrolidine
trifluoromethanesulfonic acid

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(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate. / Jones, M D; Paz, F A A; Davies, J E; Johnson, B F G.

In: Acta Crystallographica Section E-Structure Reports Online, Vol. 59, 2003, p. M105-M107.

Research output: Contribution to journalArticle

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title = "(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate",
abstract = "The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.",
author = "Jones, {M D} and Paz, {F A A} and Davies, {J E} and Johnson, {B F G}",
note = "ID number: ISI:000181609600012",
year = "2003",
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T1 - (eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

AU - Jones,M D

AU - Paz,F A A

AU - Davies,J E

AU - Johnson,B F G

N1 - ID number: ISI:000181609600012

PY - 2003

Y1 - 2003

N2 - The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

AB - The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

U2 - 10.1107/s600536803003507

DO - 10.1107/s600536803003507

M3 - Article

VL - 59

SP - M105-M107

JO - Acta Crystallographica Section E-Structure Reports Online

T2 - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

SN - 1600-5368

ER -