(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

M D Jones; F A A Paz; J E Davies; B F G Johnson

doi:10.1107/s600536803003507

(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

M D Jones, F A A Paz, J E Davies, B F G Johnson

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (SciVal)

Abstract

The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

Original language	English
Pages (from-to)	M105-M107
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	59
DOIs	https://doi.org/10.1107/s600536803003507
Publication status	Published - 2003

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ID number: ISI:000181609600012

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@article{fbb107a8286e4bb093c9f16ce855250a,

title = "(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate",

abstract = "The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.",

author = "Jones, {M D} and Paz, {F A A} and Davies, {J E} and Johnson, {B F G}",

note = "ID number: ISI:000181609600012",

year = "2003",

doi = "10.1107/s600536803003507",

language = "English",

volume = "59",

pages = "M105--M107",

journal = "Acta Crystallographica Section E-Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - (eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

AU - Jones, M D

AU - Paz, F A A

AU - Davies, J E

AU - Johnson, B F G

N1 - ID number: ISI:000181609600012

PY - 2003

Y1 - 2003

N2 - The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

AB - The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

U2 - 10.1107/s600536803003507

DO - 10.1107/s600536803003507

M3 - Article

SN - 1600-5368

VL - 59

SP - M105-M107

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

Abstract

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