(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate

M D Jones, F A A Paz, J E Davies, B F G Johnson, J Klinowski

Research output: Contribution to journalArticle

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Abstract

The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.
LanguageEnglish
PagesM538-M540
JournalActa Crystallographica Section E-Structure Reports Online
Volume59
DOIs
StatusPublished - 2003

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Methylene Chloride
Dichloromethane
Anions
Negative ions
Crystal structure
Metals
anions
crystal structure
Molecules
Geometry
geometry
metals
molecules
trifluoromethanesulfonic acid

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(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate. / Jones, M D; Paz, F A A; Davies, J E; Johnson, B F G; Klinowski, J.

In: Acta Crystallographica Section E-Structure Reports Online, Vol. 59, 2003, p. M538-M540.

Research output: Contribution to journalArticle

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abstract = "The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.",
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T1 - (eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate

AU - Jones, M D

AU - Paz, F A A

AU - Davies, J E

AU - Johnson, B F G

AU - Klinowski, J

N1 - ID number: ISI:000183875000060

PY - 2003

Y1 - 2003

N2 - The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

AB - The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

U2 - 10.1107/s1600536803012741

DO - 10.1107/s1600536803012741

M3 - Article

VL - 59

SP - M538-M540

JO - Acta Crystallographica Section E-Structure Reports Online

T2 - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

SN - 1600-5368

ER -