(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate

M D Jones; F A A Paz; J E Davies; B F G Johnson; J Klinowski

doi:10.1107/s1600536803012741

(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate

M D Jones, F A A Paz, J E Davies, B F G Johnson, J Klinowski

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (SciVal)

Abstract

The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

Original language	English
Pages (from-to)	M538-M540
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	59
DOIs	https://doi.org/10.1107/s1600536803012741
Publication status	Published - 2003

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@article{a3094a53836a4f67bc3628af7cb8e374,

title = "(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate",

abstract = "The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.",

author = "Jones, {M D} and Paz, {F A A} and Davies, {J E} and Johnson, {B F G} and J Klinowski",

note = "ID number: ISI:000183875000060",

year = "2003",

doi = "10.1107/s1600536803012741",

language = "English",

volume = "59",

pages = "M538--M540",

journal = "Acta Crystallographica Section E-Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - (eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate

AU - Jones, M D

AU - Paz, F A A

AU - Davies, J E

AU - Johnson, B F G

AU - Klinowski, J

N1 - ID number: ISI:000183875000060

PY - 2003

Y1 - 2003

N2 - The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

AB - The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

U2 - 10.1107/s1600536803012741

DO - 10.1107/s1600536803012741

M3 - Article

SN - 1600-5368

VL - 59

SP - M538-M540

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate

Abstract

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