Projects per year
Abstract
An epoxy derivative of a naturally occuring vinylphenolic compound, 4-vinylguaiacol (4VGEP), was used for the synthesis of a well-defined (Mw/Mn = 1.08–1.14), bio-based styrene-type polymer. Block copolymers of 4VGEP with styrene and diethylacrylamide were also prepared and used as macro-monomers in metal, and metal-free, ring-opening copolymerisation (ROCOP) with cis-4-cyclohexene-1,2-dicarboxylic anhydride to form ester cross-linked star polymers in high yields (82–90%), with narrow dispersity (Mw/Mn = 1.27–1.40). Finally, the selective degradation of the ester core of the styrene-based star was achieved under acidic conditions.
Original language | English |
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Pages (from-to) | 5844-5850 |
Journal | Polymer Chemistry |
Volume | 11 |
Issue number | 36 |
Early online date | 19 Aug 2020 |
DOIs | |
Publication status | Published - 28 Sept 2020 |
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Dive into the research topics of 'Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymers via a RAFT/ROCOP strategy'. Together they form a unique fingerprint.Projects
- 2 Finished
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UR Fellowship - Sugar-based Polymers for a New Generation of Sustainable Materials
Buchard, A. (PI)
1/10/17 → 30/09/22
Project: Research council
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Catalytic Production of Monomers for Sustainable Polymers from Carbon Dioxide and Diols
Buchard, A. (PI)
Engineering and Physical Sciences Research Council
1/07/16 → 31/01/18
Project: Research council