Engineering active sites for enhancing synergy in heterogeneous catalytic oxidations

James Paterson; Matthew Potter; Enrica Gianotti; Robert Raja

doi:10.1039/c0cc02341h

Engineering active sites for enhancing synergy in heterogeneous catalytic oxidations

James Paterson, Matthew Potter, Enrica Gianotti, Robert Raja

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

34 Citations (SciVal)

Abstract

The simultaneous isomorphous substitution of Al(III) and P(V) ions, in an aluminophosphate framework, with redox active Co(III) and Ti(IV) metal ions, generates highly active single-site heterogeneous catalysts that exhibit considerable synergy, compared to their corresponding monometallic analogues, in the catalytic epoxidation of olefins.

Original language	English
Pages (from-to)	517-519
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	1
Early online date	1 Nov 2010
DOIs	https://doi.org/10.1039/c0cc02341h
Publication status	Published - 6 Dec 2011

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The simultaneous isomorphous substitution of Al(III) and P(V) ions, in an aluminophosphate framework, with redox active Co(III) and Ti(IV) metal ions, generates highly active single-site heterogeneous catalysts that exhibit considerable synergy, compared to their corresponding monometallic analogues, in the catalytic epoxidation of olefins.",

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AB - The simultaneous isomorphous substitution of Al(III) and P(V) ions, in an aluminophosphate framework, with redox active Co(III) and Ti(IV) metal ions, generates highly active single-site heterogeneous catalysts that exhibit considerable synergy, compared to their corresponding monometallic analogues, in the catalytic epoxidation of olefins.

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Engineering active sites for enhancing synergy in heterogeneous catalytic oxidations

Abstract

ASJC Scopus subject areas

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