Enantioselective S‐H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides

Patrícia B. Momo, Alexandria N. Leveille, Elliot H. E. Farrar, Matthew N. Grayson, Anita E. Mattson, Antonio Carlos Bender Burtoloso

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Abstract

The first example of enantioselective S‐H insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95% ee) and yields (up to 97%) are achieved for 31 examples in S‐H insertion reactions of aryl thiols and α‐carbonyl sulfoxonium ylides.
Original languageEnglish
Pages (from-to)15554-15559
Number of pages6
JournalAngewandte Chemie-International Edition
Volume59
Issue number36
Early online date30 Apr 2020
DOIs
Publication statusPublished - 1 Sep 2020

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