Enantioselective palladium catalysed allylic substitution with sulfur-containing oxazoline ligands

C.G. Frost, Jonathan M J Williams

Research output: Contribution to journalArticle

Abstract

Enantiomerically pure sulfur/nitrogen ligands have been prepared in one step from amino alcohols and 2-(methylthio)benzonitrile. We have successfully employed these ligands for enantioselective palladium catalysed allylic substitution, with asymmetric induction of up to 80% ee.
LanguageEnglish
Pages1785-1788
Number of pages4
JournalTetrahedron: Asymmetry
Volume4
Issue number8
DOIs
StatusPublished - Aug 1993

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Palladium
Sulfur
palladium
Substitution reactions
sulfur
Ligands
Amino alcohols
substitutes
Amino Alcohols
ligands
induction
alcohols
Nitrogen
nitrogen
benzonitrile

Cite this

Enantioselective palladium catalysed allylic substitution with sulfur-containing oxazoline ligands. / Frost, C.G.; Williams, Jonathan M J.

In: Tetrahedron: Asymmetry, Vol. 4, No. 8, 08.1993, p. 1785-1788.

Research output: Contribution to journalArticle

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