Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate

P C B Page; F Marken; C Williamson; Y Chan; B R Buckley; D Bethell

doi:10.1002/adsc.200800064

Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate

P C B Page, F Marken, C Williamson, Y Chan, B R Buckley, D Bethell

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

58 Citations (SciVal)

Abstract

An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ees to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.

Original language	English
Pages (from-to)	1149-1154
Number of pages	6
Journal	Advanced Synthesis & Catalysis
Volume	350
Issue number	7-8
DOIs	https://doi.org/10.1002/adsc.200800064
Publication status	Published - 2008

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ID number: ISI:000255790100028

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10.1002/adsc.200800064

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abstract = "An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ees to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.",

author = "Page, {P C B} and F Marken and C Williamson and Y Chan and Buckley, {B R} and D Bethell",

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T1 - Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate

AU - Page, P C B

AU - Marken, F

AU - Williamson, C

AU - Chan, Y

AU - Buckley, B R

AU - Bethell, D

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PY - 2008

Y1 - 2008

N2 - An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ees to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.

AB - An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ees to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.

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DO - 10.1002/adsc.200800064

M3 - Article

SN - 1615-4150

VL - 350

SP - 1149

EP - 1154

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

IS - 7-8

ER -

Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate

Abstract

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