Enantiomerically Pure Palladacycles Derived from β‐Ketosulfoxides

José L. García‐Ruano; Ana M. González; Isabel López‐Solera; José R. Masaguer; Carmen Navarro‐Ranninger; Paul R. Raithby; Jesús H. Rodríguez

doi:10.1002/anie.199513511

Enantiomerically Pure Palladacycles Derived from β‐Ketosulfoxides

José L. García‐Ruano, Ana M. González, Isabel López‐Solera, José R. Masaguer, Carmen Navarro‐Ranninger, Paul R. Raithby, Jesús H. Rodríguez

Research output: Contribution to journal › Article › peer-review

Abstract

A trimeric palladium complex results from the reaction of Pd(OAc)₂ and the sulfoxide 1. A section of the structure of this complex, which is obtained enantiomerically pure in the (R,R) form and contains two dative and two covalent bonds to palladium, is shown at the bottom on the right. (Figure Presented.)

Original language	English
Pages (from-to)	1351-1353
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	34
Issue number	12
DOIs	https://doi.org/10.1002/anie.199513511
Publication status	Published - 7 Jul 1995

Keywords

complexes with sulfur ligands
ortho‐metalation
palladium compounds
sulfoxides

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199513511

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title = "Enantiomerically Pure Palladacycles Derived from β‐Ketosulfoxides",

abstract = "A trimeric palladium complex results from the reaction of Pd(OAc)2 and the sulfoxide 1. A section of the structure of this complex, which is obtained enantiomerically pure in the (R,R) form and contains two dative and two covalent bonds to palladium, is shown at the bottom on the right. (Figure Presented.)",

keywords = "complexes with sulfur ligands, ortho‐metalation, palladium compounds, sulfoxides",

author = "Garc{\'i}a‐Ruano, {Jos{\'e} L.} and Gonz{\'a}lez, {Ana M.} and Isabel L{\'o}pez‐Solera and Masaguer, {Jos{\'e} R.} and Carmen Navarro‐Ranninger and Raithby, {Paul R.} and Rodr{\'i}guez, {Jes{\'u}s H.}",

year = "1995",

month = jul,

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doi = "10.1002/anie.199513511",

language = "English",

volume = "34",

pages = "1351--1353",

journal = "Angewandte Chemie International Edition in English",

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T1 - Enantiomerically Pure Palladacycles Derived from β‐Ketosulfoxides

AU - García‐Ruano, José L.

AU - González, Ana M.

AU - López‐Solera, Isabel

AU - Masaguer, José R.

AU - Navarro‐Ranninger, Carmen

AU - Raithby, Paul R.

AU - Rodríguez, Jesús H.

PY - 1995/7/7

Y1 - 1995/7/7

N2 - A trimeric palladium complex results from the reaction of Pd(OAc)2 and the sulfoxide 1. A section of the structure of this complex, which is obtained enantiomerically pure in the (R,R) form and contains two dative and two covalent bonds to palladium, is shown at the bottom on the right. (Figure Presented.)

AB - A trimeric palladium complex results from the reaction of Pd(OAc)2 and the sulfoxide 1. A section of the structure of this complex, which is obtained enantiomerically pure in the (R,R) form and contains two dative and two covalent bonds to palladium, is shown at the bottom on the right. (Figure Presented.)

KW - complexes with sulfur ligands

KW - ortho‐metalation

KW - palladium compounds

KW - sulfoxides

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U2 - 10.1002/anie.199513511

DO - 10.1002/anie.199513511

M3 - Article

AN - SCOPUS:33748246663

SN - 0570-0833

VL - 34

SP - 1351

EP - 1353

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 12

ER -

Enantiomerically Pure Palladacycles Derived from β‐Ketosulfoxides

Abstract

Keywords

ASJC Scopus subject areas

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