Enantiomerically pure acetals as ligands for asymmetric catalysis

Christopher G. Frost; Jonathan M.J. Williams

doi:10.1055/s-1994-22925

Enantiomerically pure acetals as ligands for asymmetric catalysis

Christopher G. Frost, Jonathan M.J. Williams

Loughborough University

Research output: Contribution to journal › Article › peer-review

Abstract

Enantiomerically pure acetals derived from C ₂ -symmetric diols have been examined as ligands for asymmetric catalysis. Ligands in which the acetal is tethered to an auxiliary donor atom have afforded good levels of enantioselectivity in palladium catalysed allylic substitution (up to 88% ee).

Original language	English
Pages (from-to)	551-552
Number of pages	2
Journal	Synlett
Volume	1994
Issue number	7
DOIs	https://doi.org/10.1055/s-1994-22925
Publication status	Published - 1 Jul 1994

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1994-22925

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title = "Enantiomerically pure acetals as ligands for asymmetric catalysis",

abstract = " Enantiomerically pure acetals derived from C 2 -symmetric diols have been examined as ligands for asymmetric catalysis. Ligands in which the acetal is tethered to an auxiliary donor atom have afforded good levels of enantioselectivity in palladium catalysed allylic substitution (up to 88% ee). ",

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AU - Williams, Jonathan M.J.

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AB - Enantiomerically pure acetals derived from C 2 -symmetric diols have been examined as ligands for asymmetric catalysis. Ligands in which the acetal is tethered to an auxiliary donor atom have afforded good levels of enantioselectivity in palladium catalysed allylic substitution (up to 88% ee).

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DO - 10.1055/s-1994-22925

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VL - 1994

SP - 551

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JO - Synlett

JF - Synlett

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Enantiomerically pure acetals as ligands for asymmetric catalysis

Abstract

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