Electrophilic reactivity of arene carbonyl cluster complexes with the Ru6C core. Crystal and molecular structure of [Ru6C(CO)14(η6-C6H 4Ph2-1,4)]

Till Borchert; Jack Lewis; Hans Pritzkow; Paul R. Raithby; Hubert Wadepohl

doi:10.1039/DT9950001061

Electrophilic reactivity of arene carbonyl cluster complexes with the Ru₆C core. Crystal and molecular structure of [Ru₆C(CO)₁₄(η⁶-C₆H ₄Ph₂-1,4)]

Till Borchert, Jack Lewis, Hans Pritzkow, Paul R. Raithby, Hubert Wadepohl

Research output: Contribution to journal › Article › peer-review

Abstract

Addition of LiPh to [Ru₆C(CO)₁₂(η⁶-C₆H ₆)(μ-η²:η²-C₆H ₈)], [Ru₆C(CO)₁₁(η⁶-C₆H ₆)(μ₃-η²:η²:η ²-C₆H₆)] and [Ru₆C(CO)₁₄(η⁶-C₆H ₆)], followed by treatment with [CPh₃][BF₄], has led to the substituted arene cluster complexes [Ru₆C(CO)₁₂(μ-η²:η ²-C₆H₈)(η⁶-C₆H ₅Ph)], [Ru₆C(CO)₁₁(μ₃-η²:η ²:η²-C₆H₆)(η ⁶-C₆H₅-Ph)] and [Ru₆C(CO)₁₄(η⁶-C₆H ₄Ph₂-1,4)] (structure established by X-ray crystallography).

Original language	English
Pages (from-to)	1061-1062
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Volume	1995
Issue number	6
DOIs	https://doi.org/10.1039/DT9950001061
Publication status	Published - 31 Dec 1995

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Chemistry(all)

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10.1039/DT9950001061

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Electrophilic reactivity of arene carbonyl cluster complexes with the Ru₆C core. Crystal and molecular structure of [Ru₆C(CO)₁₄(η⁶-C₆H ₄Ph₂-1,4)]. / Borchert, Till; Lewis, Jack; Pritzkow, Hans; Raithby, Paul R.; Wadepohl, Hubert.

In: Journal of the Chemical Society, Dalton Transactions, Vol. 1995, No. 6, 31.12.1995, p. 1061-1062.

Research output: Contribution to journal › Article › peer-review

@article{325aa14daf794243b033688d556be399,

title = "Electrophilic reactivity of arene carbonyl cluster complexes with the Ru6C core. Crystal and molecular structure of [Ru6C(CO)14(η6-C6H 4Ph2-1,4)]",

abstract = "Addition of LiPh to [Ru6C(CO)12(η6-C6H 6)(μ-η2:η2-C6H 8)], [Ru6C(CO)11(η6-C6H 6)(μ3-η2:η2:η 2-C6H6)] and [Ru6C(CO)14(η6-C6H 6)], followed by treatment with [CPh3][BF4], has led to the substituted arene cluster complexes [Ru6C(CO)12(μ-η2:η 2-C6H8)(η6-C6H 5Ph)], [Ru6C(CO)11(μ3-η2:η 2:η2-C6H6)(η 6-C6H5-Ph)] and [Ru6C(CO)14(η6-C6H 4Ph2-1,4)] (structure established by X-ray crystallography).",

author = "Till Borchert and Jack Lewis and Hans Pritzkow and Raithby, {Paul R.} and Hubert Wadepohl",

year = "1995",

month = dec,

day = "31",

doi = "10.1039/DT9950001061",

language = "English",

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pages = "1061--1062",

journal = "Dalton Transactions ",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Electrophilic reactivity of arene carbonyl cluster complexes with the Ru6C core. Crystal and molecular structure of [Ru6C(CO)14(η6-C6H 4Ph2-1,4)]

AU - Borchert, Till

AU - Lewis, Jack

AU - Pritzkow, Hans

AU - Raithby, Paul R.

AU - Wadepohl, Hubert

PY - 1995/12/31

Y1 - 1995/12/31

N2 - Addition of LiPh to [Ru6C(CO)12(η6-C6H 6)(μ-η2:η2-C6H 8)], [Ru6C(CO)11(η6-C6H 6)(μ3-η2:η2:η 2-C6H6)] and [Ru6C(CO)14(η6-C6H 6)], followed by treatment with [CPh3][BF4], has led to the substituted arene cluster complexes [Ru6C(CO)12(μ-η2:η 2-C6H8)(η6-C6H 5Ph)], [Ru6C(CO)11(μ3-η2:η 2:η2-C6H6)(η 6-C6H5-Ph)] and [Ru6C(CO)14(η6-C6H 4Ph2-1,4)] (structure established by X-ray crystallography).

AB - Addition of LiPh to [Ru6C(CO)12(η6-C6H 6)(μ-η2:η2-C6H 8)], [Ru6C(CO)11(η6-C6H 6)(μ3-η2:η2:η 2-C6H6)] and [Ru6C(CO)14(η6-C6H 6)], followed by treatment with [CPh3][BF4], has led to the substituted arene cluster complexes [Ru6C(CO)12(μ-η2:η 2-C6H8)(η6-C6H 5Ph)], [Ru6C(CO)11(μ3-η2:η 2:η2-C6H6)(η 6-C6H5-Ph)] and [Ru6C(CO)14(η6-C6H 4Ph2-1,4)] (structure established by X-ray crystallography).

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U2 - 10.1039/DT9950001061

DO - 10.1039/DT9950001061

M3 - Article

AN - SCOPUS:37049075365

VL - 1995

SP - 1061

EP - 1062

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 6