TY - JOUR
T1 - Electrophilic reactivity of arene carbonyl cluster complexes with the Ru6C core. Crystal and molecular structure of [Ru6C(CO)14(η6-C6H 4Ph2-1,4)]
AU - Borchert, Till
AU - Lewis, Jack
AU - Pritzkow, Hans
AU - Raithby, Paul R.
AU - Wadepohl, Hubert
PY - 1995/12/31
Y1 - 1995/12/31
N2 - Addition of LiPh to [Ru6C(CO)12(η6-C6H 6)(μ-η2:η2-C6H 8)], [Ru6C(CO)11(η6-C6H 6)(μ3-η2:η2:η 2-C6H6)] and [Ru6C(CO)14(η6-C6H 6)], followed by treatment with [CPh3][BF4], has led to the substituted arene cluster complexes [Ru6C(CO)12(μ-η2:η 2-C6H8)(η6-C6H 5Ph)], [Ru6C(CO)11(μ3-η2:η 2:η2-C6H6)(η 6-C6H5-Ph)] and [Ru6C(CO)14(η6-C6H 4Ph2-1,4)] (structure established by X-ray crystallography).
AB - Addition of LiPh to [Ru6C(CO)12(η6-C6H 6)(μ-η2:η2-C6H 8)], [Ru6C(CO)11(η6-C6H 6)(μ3-η2:η2:η 2-C6H6)] and [Ru6C(CO)14(η6-C6H 6)], followed by treatment with [CPh3][BF4], has led to the substituted arene cluster complexes [Ru6C(CO)12(μ-η2:η 2-C6H8)(η6-C6H 5Ph)], [Ru6C(CO)11(μ3-η2:η 2:η2-C6H6)(η 6-C6H5-Ph)] and [Ru6C(CO)14(η6-C6H 4Ph2-1,4)] (structure established by X-ray crystallography).
UR - http://www.scopus.com/inward/record.url?scp=37049075365&partnerID=8YFLogxK
U2 - 10.1039/DT9950001061
DO - 10.1039/DT9950001061
M3 - Article
AN - SCOPUS:37049075365
SN - 1472-7773
VL - 1995
SP - 1061
EP - 1062
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 6
ER -