Electrochemically promoted Friedel-Crafts acylation of aromatic compounds

G Karthik; K Kulangiappar; F Marken; A A Kulandainathan

doi:10.1016/j.tetlet.2008.02.084

Electrochemically promoted Friedel-Crafts acylation of aromatic compounds

G Karthik, K Kulangiappar, F Marken, A A Kulandainathan

Department of Chemistry

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3 Citations (SciVal)

Abstract

Friedel-Crafts acylation is carried out with several aromatic substrates in the presence of an electrochemically active aluminium anode to minimize the inorganic reagents. Only a catalytic amount of AlCl3 (5 mol %) is required to enable the anodic polarization of the aluminium electrode to promote continuous acylation. This process typically gave products in good yields (70-96%). (C) 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2625-2627
Number of pages	3
Journal	Tetrahedron Letters
Volume	49
Issue number	16
DOIs	https://doi.org/10.1016/j.tetlet.2008.02.084
Publication status	Published - 2008

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ID number: ISI:000255318800031

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10.1016/j.tetlet.2008.02.084

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abstract = "Friedel-Crafts acylation is carried out with several aromatic substrates in the presence of an electrochemically active aluminium anode to minimize the inorganic reagents. Only a catalytic amount of AlCl3 (5 mol \%) is required to enable the anodic polarization of the aluminium electrode to promote continuous acylation. This process typically gave products in good yields (70-96\%). (C) 2008 Elsevier Ltd. All rights reserved.",

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AU - Kulangiappar, K

AU - Marken, F

AU - Kulandainathan, A A

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AB - Friedel-Crafts acylation is carried out with several aromatic substrates in the presence of an electrochemically active aluminium anode to minimize the inorganic reagents. Only a catalytic amount of AlCl3 (5 mol %) is required to enable the anodic polarization of the aluminium electrode to promote continuous acylation. This process typically gave products in good yields (70-96%). (C) 2008 Elsevier Ltd. All rights reserved.

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DO - 10.1016/j.tetlet.2008.02.084

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Electrochemically promoted Friedel-Crafts acylation of aromatic compounds

Abstract

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