Electrochemical detection of as(III) via iodine electrogenerated at platinum, gold, diamond or carbon-based electrodes

Geraldine Hignett; Jay D. Wadhawan; Nathan S. Lawrence; Dang Q. Hung; César Prado; Frank Marken; Richard G. Compton

doi:10.1002/elan.200302903

Electrochemical detection of as(III) via iodine electrogenerated at platinum, gold, diamond or carbon-based electrodes

Geraldine Hignett, Jay D. Wadhawan, Nathan S. Lawrence, Dang Q. Hung, César Prado, Frank Marken, Richard G. Compton

Research output: Contribution to journal › Article › peer-review

42 Citations (SciVal)

Abstract

The reaction of iodine, electrogenerated from iodide, is used for the detection of As(III) via electrocatalytic reaction in the diffusion layer of a boron-doped diamond electrode. The merits of this electrode material for this purpose (over platinum, gold or glassy carbon) are demonstrated and the kinetics of the reaction between I₂ and As(III) in acid reported.

Original language	English
Pages (from-to)	897-903
Number of pages	7
Journal	Electroanalysis
Volume	16
Issue number	11
DOIs	https://doi.org/10.1002/elan.200302903
Publication status	Published - 1 Jun 2004

Keywords

Arsenic
Boron-doped diamond
Electrocatalysis
Iodine
pH

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

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10.1002/elan.200302903

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abstract = "The reaction of iodine, electrogenerated from iodide, is used for the detection of As(III) via electrocatalytic reaction in the diffusion layer of a boron-doped diamond electrode. The merits of this electrode material for this purpose (over platinum, gold or glassy carbon) are demonstrated and the kinetics of the reaction between I2 and As(III) in acid reported.",

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AU - Hignett, Geraldine

AU - Wadhawan, Jay D.

AU - Lawrence, Nathan S.

AU - Hung, Dang Q.

AU - Prado, César

AU - Marken, Frank

AU - Compton, Richard G.

PY - 2004/6/1

Y1 - 2004/6/1

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AB - The reaction of iodine, electrogenerated from iodide, is used for the detection of As(III) via electrocatalytic reaction in the diffusion layer of a boron-doped diamond electrode. The merits of this electrode material for this purpose (over platinum, gold or glassy carbon) are demonstrated and the kinetics of the reaction between I2 and As(III) in acid reported.

KW - Arsenic

KW - Boron-doped diamond

KW - Electrocatalysis

KW - Iodine

KW - pH

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ER -

Electrochemical detection of as(III) via iodine electrogenerated at platinum, gold, diamond or carbon-based electrodes

Abstract

Keywords

ASJC Scopus subject areas

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