Electrochemical deconstructive functionalization of arylcycloalkanes via fragmentation of anodically generated aromatic radical cations

Hussain A. Maashi, Abdulrahman H. Husayni, James Harnedy, Louis C. Morrill

Research output: Contribution to journalReview articlepeer-review

1 Citation (SciVal)

Abstract

This highlight summarises electrochemical approaches for the deconstructive functionalization of arylcycloalkanes via the fragmentation of anodically generated aromatic radical cations. A diverse range of deconstructive functionalization processes is described, including discussion on the electrochemical reaction conditions employed, scope and limitations, and reaction mechanisms, in addition to highlighting future opportunities in this burgeoning area of sustainable synthesis.

Original languageEnglish
Pages (from-to)11190-11201
Number of pages12
JournalChemical Communications
Volume60
Issue number80
Early online date13 Sept 2024
DOIs
Publication statusPublished - 13 Sept 2024

Data Availability Statement

No primary research results have been included and no new data were generated or analysed as part of this review.

Acknowledgements

We gratefully acknowledge the School of Chemistry at Cardiff University and the Department of Chemistry at the University of Bath for generous support. We also thank the Saudi Arabia cultural mission in the UK and the Department of Chemistry at the University of Bisha (H. A. M.) and the Department of Chemistry at Jazan University (A. H. H.) for PhD studentships.

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Catalysis
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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