Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

T Thorpe; J Blacker; S M Brown; C Bubert; J Crosby; S Fitzjohn; J P Muxworthy; J M J Williams

doi:10.1016/s0040-4039(01)00624-4

Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

T Thorpe
, J Blacker
, S M Brown
, C Bubert
, J Crosby
, S Fitzjohn
, J P Muxworthy
, J M J Williams

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

120 Citations (SciVal)

Abstract

A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	4041-4043
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	24
DOIs	https://doi.org/10.1016/s0040-4039(01)00624-4
Publication status	Published - 2001

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ID number: ISI:000169116400021

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title = "Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands",

abstract = "A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51\% water. (C) 2001 Elsevier Science Ltd. All rights reserved.",

author = "T Thorpe and J Blacker and Brown, \{S M\} and C Bubert and J Crosby and S Fitzjohn and Muxworthy, \{J P\} and Williams, \{J M J\}",

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T1 - Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

AU - Thorpe, T

AU - Blacker, J

AU - Brown, S M

AU - Bubert, C

AU - Crosby, J

AU - Fitzjohn, S

AU - Muxworthy, J P

AU - Williams, J M J

N1 - ID number: ISI:000169116400021

PY - 2001

Y1 - 2001

N2 - A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

U2 - 10.1016/s0040-4039(01)00624-4

DO - 10.1016/s0040-4039(01)00624-4

M3 - Article

SN - 0040-4039

VL - 42

SP - 4041

EP - 4043

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 24

ER -

Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

Abstract

Bibliographical note

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