Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

T Thorpe; J Blacker; S M Brown; C Bubert; J Crosby; S Fitzjohn; J P Muxworthy; J M J Williams

Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

T Thorpe, J Blacker, S M Brown, C Bubert, J Crosby, S Fitzjohn, J P Muxworthy, J M J Williams

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

115 Citations (SciVal)

Abstract

A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	4041-4043
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	24
Publication status	Published - 2001

Bibliographical note

ID number: ISI:000169116400021

Cite this

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title = "Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands",

abstract = "A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.",

author = "T Thorpe and J Blacker and Brown, {S M} and C Bubert and J Crosby and S Fitzjohn and Muxworthy, {J P} and Williams, {J M J}",

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year = "2001",

language = "English",

volume = "42",

pages = "4041--4043",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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number = "24",

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TY - JOUR

T1 - Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

AU - Thorpe, T

AU - Blacker, J

AU - Brown, S M

AU - Bubert, C

AU - Crosby, J

AU - Fitzjohn, S

AU - Muxworthy, J P

AU - Williams, J M J

N1 - ID number: ISI:000169116400021

PY - 2001

Y1 - 2001

N2 - A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

M3 - Article

SN - 0040-4039

VL - 42

SP - 4041

EP - 4043

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 24

ER -

Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

Abstract

Bibliographical note

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