Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate

C.J. Chapman; C.G. Frost; J.P. Hartley; A.J. Whittle

doi:10.1016/S0040-4039(00)02122-5

Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate

C.J. Chapman, C.G. Frost, J.P. Hartley, A.J. Whittle

Syngenta Ltd

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Abstract

The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an indium-catalysed ketalisation reaction.

Original language	English
Pages (from-to)	773-775
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4039(00)02122-5
Publication status	Published - 29 Jan 2001

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title = "Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate",

abstract = "The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an indium-catalysed ketalisation reaction.",

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AU - Chapman, C.J.

AU - Frost, C.G.

AU - Hartley, J.P.

AU - Whittle, A.J.

PY - 2001/1/29

Y1 - 2001/1/29

N2 - The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an indium-catalysed ketalisation reaction.

AB - The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an indium-catalysed ketalisation reaction.

UR - https://www.scopus.com/pages/publications/0035966593

UR - http://dx.doi.org/10.1016/S0040-4039(00)02122-5

U2 - 10.1016/S0040-4039(00)02122-5

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SP - 773

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate

Abstract

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