Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate

C.J. Chapman, C.G. Frost, J.P. Hartley, A.J. Whittle

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an indium-catalysed ketalisation reaction.
Original languageEnglish
Pages (from-to)773-775
Number of pages3
JournalTetrahedron Letters
Volume42
Issue number5
DOIs
Publication statusPublished - 29 Jan 2001

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Acylation
Indium
Acetone
Byproducts
Alcohols
Electrons
lithium perchlorate
isopropenyl acetate

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Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate. / Chapman, C.J.; Frost, C.G.; Hartley, J.P.; Whittle, A.J.

In: Tetrahedron Letters, Vol. 42, No. 5, 29.01.2001, p. 773-775.

Research output: Contribution to journalArticle

Chapman, C.J. ; Frost, C.G. ; Hartley, J.P. ; Whittle, A.J. / Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate. In: Tetrahedron Letters. 2001 ; Vol. 42, No. 5. pp. 773-775.
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