Abstract
This paper demonstrates the key role of the property-structure relationship of the support on iron/ceria catalysts on the hydrocarbon selectivity and olefin-to-paraffin ratio for the direct hydrogenation of carbon dioxide into hydrocarbons. The effect is directly related to the reducibility of the different nanostructured ceria supports and their interaction with the iron particles. Herein, we demonstrate that the iron-based catalysts can be modified not only by the addition of promoters, commonly reported in the literature, but also by careful control of the morphology of the ceria support.
| Original language | English |
|---|---|
| Pages (from-to) | 15496-15500 |
| Number of pages | 5 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 18 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 2 Feb 2016 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Physics and Astronomy(all)
Cite this
Effect of nanostructured ceria as support for the iron catalysed hydrogenation of CO2 into hydrocarbons. / Torrente Murciano, Laura; Chapman, Robert S L; Narvaez-Dinamarca, Ana; Mattia, Davide; Jones, Matthew.
In: Physical Chemistry Chemical Physics , Vol. 18, No. 23, 02.02.2016, p. 15496-15500.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Effect of nanostructured ceria as support for the iron catalysed hydrogenation of CO2 into hydrocarbons
AU - Torrente Murciano, Laura
AU - Chapman, Robert S L
AU - Narvaez-Dinamarca, Ana
AU - Mattia, Davide
AU - Jones, Matthew
PY - 2016/2/2
Y1 - 2016/2/2
N2 - This paper demonstrates the key role of the property-structure relationship of the support on iron/ceria catalysts on the hydrocarbon selectivity and olefin-to-paraffin ratio for the direct hydrogenation of carbon dioxide into hydrocarbons. The effect is directly related to the reducibility of the different nanostructured ceria supports and their interaction with the iron particles. Herein, we demonstrate that the iron-based catalysts can be modified not only by the addition of promoters, commonly reported in the literature, but also by careful control of the morphology of the ceria support.
AB - This paper demonstrates the key role of the property-structure relationship of the support on iron/ceria catalysts on the hydrocarbon selectivity and olefin-to-paraffin ratio for the direct hydrogenation of carbon dioxide into hydrocarbons. The effect is directly related to the reducibility of the different nanostructured ceria supports and their interaction with the iron particles. Herein, we demonstrate that the iron-based catalysts can be modified not only by the addition of promoters, commonly reported in the literature, but also by careful control of the morphology of the ceria support.
UR - http://www.scopus.com/inward/record.url?scp=84973864277&partnerID=8YFLogxK
U2 - 10.1039/c5cp07788e
DO - 10.1039/c5cp07788e
M3 - Article
VL - 18
SP - 15496
EP - 15500
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 23
ER -