Abstract
This paper demonstrates the key role of the property-structure relationship of the support on iron/ceria catalysts on the hydrocarbon selectivity and olefin-to-paraffin ratio for the direct hydrogenation of carbon dioxide into hydrocarbons. The effect is directly related to the reducibility of the different nanostructured ceria supports and their interaction with the iron particles. Herein, we demonstrate that the iron-based catalysts can be modified not only by the addition of promoters, commonly reported in the literature, but also by careful control of the morphology of the ceria support.
| Original language | English |
|---|---|
| Pages (from-to) | 15496-15500 |
| Number of pages | 5 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 18 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 2 Feb 2016 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Physics and Astronomy(all)
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Torrente Murciano, L., Chapman, R. S. L., Narvaez-Dinamarca, A., Mattia, D., & Jones, M. (2016). Effect of nanostructured ceria as support for the iron catalysed hydrogenation of CO2 into hydrocarbons. Physical Chemistry Chemical Physics , 18(23), 15496-15500. https://doi.org/10.1039/c5cp07788e