Double insertion of CO2 into an Al–Te multiple bond

Matthew Evans; Mathew Anker; Claire McMullin; Nasir Rajabi; Martyn  Coles

doi:10.1039/D0CC07448A

Double insertion of CO2 into an Al–Te multiple bond

Matthew Evans, Mathew Anker, Claire McMullin, Nasir Rajabi, Martyn Coles

Department of Chemistry

Victoria University of Wellington

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Abstract

We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

Original language	English
Pages (from-to)	2673-2676
Journal	Chemical Communications
Volume	57
Issue number	21
Early online date	2 Feb 2021
DOIs	https://doi.org/10.1039/D0CC07448A
Publication status	Published - 14 Mar 2021

Funding

MJE acknowledges a Victoria University of Wellington (VUW) Doctoral Scholarship. This research made use of the Balena High Performance Computing (HPC) Service at the University of Bath. Financial support from the EPSRC (EP/R020752/1 – NAR and CLM) and a University Research Fund grant from VUW (MDA).

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10.1039/D0CC07448A

CC-COM-11-2020-007448_correctedAccepted author manuscript, 8.89 MB

Cite this

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title = "Double insertion of CO2 into an Al–Te multiple bond",

abstract = " We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand. ",

author = "Matthew Evans and Mathew Anker and Claire McMullin and Nasir Rajabi and Martyn Coles",

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AU - Evans, Matthew

AU - Anker, Mathew

AU - McMullin, Claire

AU - Rajabi, Nasir

AU - Coles, Martyn

PY - 2021/3/14

Y1 - 2021/3/14

N2 - We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

AB - We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

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UR - https://www.scopus.com/pages/publications/85102393299

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DO - 10.1039/D0CC07448A

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VL - 57

SP - 2673

EP - 2676

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Double insertion of CO2 into an Al–Te multiple bond

Abstract

Funding

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Nucleophilic alkaline earth boryls: from conception and theory to application

Balena High Performance Computing (HPC) System

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Double insertion of CO2 into an Al–Te multiple bond

Abstract

Funding

Access to Document

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Fingerprint

Projects

Nucleophilic alkaline earth boryls: from conception and theory to application

Equipment

Balena High Performance Computing (HPC) System

Cite this