Double insertion of CO2 into an Al–Te multiple bond

Matthew Evans; Mathew Anker; Claire McMullin; Nasir Rajabi; Martyn  Coles

doi:10.1039/D0CC07448A

Double insertion of CO2 into an Al–Te multiple bond

Matthew Evans, Mathew Anker, Claire McMullin, Nasir Rajabi, Martyn Coles

Department of Chemistry

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Abstract

We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

Original language	English
Pages (from-to)	2673-2676
Journal	Chemical Communications
Volume	57
Issue number	21
Early online date	2 Feb 2021
DOIs	https://doi.org/10.1039/D0CC07448A
Publication status	Published - 14 Mar 2021

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10.1039/D0CC07448A

CC-COM-11-2020-007448_correctedAccepted author manuscript, 8.89 MB

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title = "Double insertion of CO2 into an Al–Te multiple bond",

abstract = "We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.",

author = "Matthew Evans and Mathew Anker and Claire McMullin and Nasir Rajabi and Martyn Coles",

year = "2021",

month = mar,

day = "14",

doi = "10.1039/D0CC07448A",

language = "English",

volume = "57",

pages = "2673--2676",

journal = "Chemical communications (Cambridge, England)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Double insertion of CO2 into an Al–Te multiple bond

AU - Evans, Matthew

AU - Anker, Mathew

AU - McMullin, Claire

AU - Rajabi, Nasir

AU - Coles, Martyn

PY - 2021/3/14

Y1 - 2021/3/14

N2 - We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

AB - We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

UR - https://pubs.rsc.org/en/Content/ArticleLanding/2021/CC/D0CC07448A#!divAbstract

U2 - 10.1039/D0CC07448A

DO - 10.1039/D0CC07448A

M3 - Article

VL - 57

SP - 2673

EP - 2676

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

SN - 1359-7345

IS - 21

ER -

Double insertion of CO2 into an Al–Te multiple bond

Abstract

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