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Abstract
We report the [Al(NONDipp)(Te)(THF)]− anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al–Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.
Original language | English |
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Pages (from-to) | 2673-2676 |
Journal | Chemical Communications |
Volume | 57 |
Issue number | 21 |
Early online date | 2 Feb 2021 |
DOIs | |
Publication status | Published - 14 Mar 2021 |
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Dive into the research topics of 'Double insertion of CO2 into an Al–Te multiple bond'. Together they form a unique fingerprint.Projects
- 1 Finished
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Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council
Equipment
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Balena High Performance Computing (HPC) System
Facility/equipment: Equipment