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Abstract
The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.
Original language | English |
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Pages (from-to) | 10711-10714 |
Number of pages | 4 |
Journal | Chemical communications (Cambridge, England) |
Volume | 58 |
Issue number | 76 |
Early online date | 30 Aug 2022 |
DOIs | |
Publication status | Published - 28 Sept 2022 |
Bibliographical note
We acknowledge financial support from the EPSRC (research grant EP/R020752/1) and the Petroleum Technology Development Fund (PTDF) of Nigeria for the provision of a PhD scholarship for BO-E. This research made use of the Anatra High Throughput Computing (HTC) Cluster at the University of Bath.ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Dive into the research topics of 'Diverse Reactivity of a Magnesium Silanide toward Ketones'. Together they form a unique fingerprint.Projects
- 1 Finished
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Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council