Diverse Reactivity of a Magnesium Silanide toward Ketones

Michael Hill; Bibian Okokhere-Edeghoghon; Mary Mahon; Claire McMullin

doi:10.1039/D2CC03966D

Diverse Reactivity of a Magnesium Silanide toward Ketones

Michael Hill, Bibian Okokhere-Edeghoghon, Mary Mahon, Claire McMullin

Research output: Contribution to journal › Article › peer-review

2 Citations (SciVal)

Abstract

The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.

Original language	English
Pages (from-to)	10711-10714
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	58
Issue number	76
Early online date	30 Aug 2022
DOIs	https://doi.org/10.1039/D2CC03966D
Publication status	Published - 28 Sept 2022

Bibliographical note

We acknowledge financial support from the EPSRC (research grant EP/R020752/1) and the Petroleum Technology Development Fund (PTDF) of Nigeria for the provision of a PhD scholarship for BO-E. This research made use of the Anatra High Throughput Computing (HTC) Cluster at the University of Bath.

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/D2CC03966DLicence: CC BY

Cite this

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abstract = "The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.",

author = "Michael Hill and Bibian Okokhere-Edeghoghon and Mary Mahon and Claire McMullin",

note = "We acknowledge financial support from the EPSRC (research grant EP/R020752/1) and the Petroleum Technology Development Fund (PTDF) of Nigeria for the provision of a PhD scholarship for BO-E. This research made use of the Anatra High Throughput Computing (HTC) Cluster at the University of Bath.",

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N1 - We acknowledge financial support from the EPSRC (research grant EP/R020752/1) and the Petroleum Technology Development Fund (PTDF) of Nigeria for the provision of a PhD scholarship for BO-E. This research made use of the Anatra High Throughput Computing (HTC) Cluster at the University of Bath.

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Diverse Reactivity of a Magnesium Silanide toward Ketones

Abstract

Bibliographical note

ASJC Scopus subject areas

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Nucleophilic alkaline earth boryls: from conception and theory to application

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Diverse Reactivity of a Magnesium Silanide toward Ketones

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

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Nucleophilic alkaline earth boryls: from conception and theory to application

Cite this