Diverse Reactivity of a Magnesium Silanide toward Ketones

Michael Hill; Bibian Okokhere-Edeghoghon; Mary Mahon; Claire McMullin

doi:10.1039/D2CC03966D

Diverse Reactivity of a Magnesium Silanide toward Ketones

Michael Hill, Bibian Okokhere-Edeghoghon, Mary Mahon, Claire McMullin

Research output: Contribution to journal › Article › peer-review

Abstract

The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.

Original language	English
Pages (from-to)	10711-10714
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	58
Issue number	76
Early online date	30 Aug 2022
DOIs	https://doi.org/10.1039/D2CC03966D
Publication status	Published - 28 Sept 2022

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/D2CC03966DLicence: CC BY

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abstract = "The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.",

author = "Michael Hill and Bibian Okokhere-Edeghoghon and Mary Mahon and Claire McMullin",

note = "We acknowledge financial support from the EPSRC (research grant EP/R020752/1) and the Petroleum Technology Development Fund (PTDF) of Nigeria for the provision of a PhD scholarship for BO-E. This research made use of the Anatra High Throughput Computing (HTC) Cluster at the University of Bath.",

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Diverse Reactivity of a Magnesium Silanide toward Ketones

Abstract

ASJC Scopus subject areas

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Nucleophilic alkaline earth boryls: from conception and theory to application

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Diverse Reactivity of a Magnesium Silanide toward Ketones

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ASJC Scopus subject areas

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Nucleophilic alkaline earth boryls: from conception and theory to application

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